Introduction To Quantum Mechanics
Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Chapter 11.5, Problem 11.18P

(a)

To determine

The density matrix for an electron that is either in the state spin up along x or in the spin down along y.

(b)

To determine

The value of Sy for an electron.

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Write down the equations and the associated boundary conditions for solving particle in a 1-D box of dimension L with a finite potential well, i.e., the potential energy U is zero inside the box, but finite outside the box. Specifically, U = U₁ for x L. Assuming that particle's energy E is less than U, what form do the solutions take? Without solving the problem (feel free to give it a try though), qualitatively compare with the case with infinitely hard walls by sketching the differences in wave functions and probability densities and describing the changes in particle momenta and energy levels (e.g., increasing or decreasing and why), for a given quantum number.
Problem 2.3 Show that there is no acceptable solution to the (time-independent) Schrödinger equation for the infinite square well with E = 0 or E < 0. (This is a special case of the general theorem in Problem 2.2, but this time do it by explicitly solving the Schrödinger equation, and showing that you cannot satisfy the boundary conditions.)
Question 2 2.1 Consider an infinite well for which the bottom is not flat, as sketched here. If the slope is small, the potential V = 6 |x|/ a may be considered as a perturbation on the square- well potential over -a/2 ≤x≤a/2. -8 W V(x) a/2 -a/2 X Calculate the ground-state energy, correct to first order in perturbation theory. Given (0) = √²/co COS Ground state of box of size a: = Ground state energy: E(0) = 4²k² 2ma². 0 Y
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