Introduction To Quantum Mechanics
3rd Edition
ISBN: 9781107189638
Author: Griffiths, David J., Schroeter, Darrell F.
Publisher: Cambridge University Press
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Question
Chapter 11, Problem 11.26P
(a)
To determine
Solve for the function
(b)
To determine
Analyze the same situation above using the first order perturbation theory and compare the results.
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Starting with the equation of motion of a three-dimensional isotropic harmonic
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dt
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dt
where
1
P.P, +kr,r,.
2m
(Note that we will use the notations r,, r2, r, and a, y, z interchangeably, and similarly
for the components of p.)
Let V (r1→, ..., rM→) be the potential energy of a system of M massive particles which has the scaling property:V (α r1→, ..., α rM→) = αk V (r1→, ..., rM→)(k is usually an integer, α an arbitrary constant.) Prove that, if the Lagrangianis to remain invariant (except for multiplication by a constant), and all distances are scaled by a factor α, then the time must be scaled by a factor:
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[x(1) B(2) + B(1) a(2)]
Which of the following statements is incorrect concerning p(1,2) ?
a.
W(1,2) is normalized.
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The function W(1,2) is symmetric with respect to the exchange of the space and the spin coordinates of the two electrons.
OC.
y(1,2) is an eigenfunction of the reference (or zero-order) Hamiltonian (in which the electron-electron repulsion term is ignored) of Li with
eigenvalue = -5 hartree.
d.
The function y(1,2) is an acceptable wave function to describe the properties of one of the excited states of Lit.
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Chapter 11 Solutions
Introduction To Quantum Mechanics
Ch. 11.1 - Prob. 11.1PCh. 11.1 - Prob. 11.2PCh. 11.1 - Prob. 11.3PCh. 11.1 - Prob. 11.4PCh. 11.1 - Prob. 11.5PCh. 11.1 - Prob. 11.6PCh. 11.1 - Prob. 11.7PCh. 11.1 - Prob. 11.8PCh. 11.1 - Prob. 11.9PCh. 11.3 - Prob. 11.10P
Ch. 11.3 - Prob. 11.11PCh. 11.3 - Prob. 11.12PCh. 11.3 - Prob. 11.13PCh. 11.3 - Prob. 11.14PCh. 11.3 - Prob. 11.15PCh. 11.3 - Prob. 11.16PCh. 11.4 - Prob. 11.17PCh. 11.5 - Prob. 11.18PCh. 11.5 - Prob. 11.19PCh. 11.5 - Prob. 11.20PCh. 11.5 - Prob. 11.21PCh. 11.5 - Prob. 11.22PCh. 11 - Prob. 11.23PCh. 11 - Prob. 11.24PCh. 11 - Prob. 11.25PCh. 11 - Prob. 11.26PCh. 11 - Prob. 11.27PCh. 11 - Prob. 11.28PCh. 11 - Prob. 11.29PCh. 11 - Prob. 11.30PCh. 11 - Prob. 11.31PCh. 11 - Prob. 11.33PCh. 11 - Prob. 11.35PCh. 11 - Prob. 11.36PCh. 11 - Prob. 11.37P
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