It is to be determined and explained if the nucleophilic addition step between HO - and CH 3 COCl will be allowed if HO - were to approach the carbonyl C atom directly along the C=O bond. Concept introduction: When two orbitals overlap with the same phases, constructive interference takes place. When two orbitals overlap with the opposite phases, destructive interference takes place. Constructive interference results in a new orbital that is more stable than the σ bonding orbital, and destructive interference results in a new orbital that is less stable than the p atomic orbital.

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Chapter D, Problem D.7P

Interpretation Introduction

Interpretation:

It is to be determined and explained if the nucleophilic addition step between HO- and CH3COCl will be allowed if HO- were to approach the carbonyl C atom directly along the C=O bond.

Concept introduction:

When two orbitals overlap with the same phases, constructive interference takes place. When two orbitals overlap with the opposite phases, destructive interference takes place. Constructive interference results in a new orbital that is more stable than the σ bonding orbital, and destructive interference results in a new orbital that is less stable than the p atomic orbital.

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