EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Chapter D, Problem D.14YT
Interpretation Introduction
Interpretation:
Every region of constructive interference and destructive interference between the HOMO and LUMO in the Figure
Concept introduction:
The overlapping of AOs of two atoms results in the formation of molecular orbitals. When two orbitals overlap with the same phases, constructive interference takes place. When two orbitals overlap with the opposite phases, destructive interference takes place.
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Follow the instructions on the first picture and answer letter a to g using the given problem on the second picture.
2. According to the Beer-Lambert law absorbance is proportional
to concentration at each wavelength. In principle, one could
choose any wavelength for quantitative estimations of
concentration. However, we generally select the wavelength of
maximum absorbance for a given sample and use it in our
absorbance measurements. Especially, one should avoid the
steep portions of the spectrum. Why?
3. Which concentration range
a dilute or a concentrated one - is
chosen for accurate determinations of unknown concentrations?
Here is the visible absorbance spectrum and electromagnetic spectrum.
1. Determine which molecule (a,b,c, or d) has the smaller HOMO-LUMO gap. Briefly explainyour reasoning. rememeber more conjugation is a smaller gap.
Chapter D Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. D - Prob. D.1PCh. D - Prob. D.2PCh. D - Prob. D.3PCh. D - Prob. D.4PCh. D - Prob. D.5PCh. D - Prob. D.6PCh. D - Prob. D.7PCh. D - Prob. D.8PCh. D - Prob. D.9PCh. D - Prob. D.10P
Ch. D - Prob. D.11PCh. D - Prob. D.1YTCh. D - Prob. D.2YTCh. D - Prob. D.3YTCh. D - Prob. D.4YTCh. D - Prob. D.5YTCh. D - Prob. D.6YTCh. D - Prob. D.7YTCh. D - Prob. D.8YTCh. D - Prob. D.9YTCh. D - Prob. D.10YTCh. D - Prob. D.11YTCh. D - Prob. D.12YTCh. D - Prob. D.13YTCh. D - Prob. D.14YTCh. D - Prob. D.15YTCh. D - Prob. D.16YT
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- please provide the correct answer for this but with lot of detail thank youarrow_forwardThis absorbance value (no wavelength where the maximum absorption occurs) corresponds to what % Transmittance value?arrow_forwardExplain why this is correct. Also explain what a chromophore is and what is its distinigusiing characteristics. If I wanted to pick out a chromophore, what structure would I be looking for. Please answer fast i give you upvote.arrow_forward
- Chemistry label the ir for this molecule.arrow_forwardAll the atoms in a conjugated system are _. The fewer electrons involved in the conjugated system, the energy gap between HOMO and LUMO will be _. and therefore the wavelength of the photon involved in the absorption process will be _. Being the energy of the HOMO _ than LUMO's, the process of absorption will take place when an electron goes from _. Considering the molecule on the left, there are _ carbon atoms forming a conjugated system. The picture on the right _ a resonance form of the picture on the left.arrow_forwardCould you please help me with this MCQs?arrow_forward
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