EBK GET READY FOR ORGANIC CHEMISTRY
EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 8220100576379
Author: KARTY
Publisher: PEARSON
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Chapter C, Problem C.2P
Interpretation Introduction

(a)

Interpretation:

The substituents in the given set are to be reordered from highest to lowest priority.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has higher priority. In case of comparison between isotopes, the one having the greater atomic mass gets higher priority.

Interpretation Introduction

(b)

Interpretation:

The substituents in the given set are to be reordered from highest to lowest priority.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has higher priority. In case of comparison between isotopes, the one having the greater atomic mass gets higher priority.

Interpretation Introduction

(c)

Interpretation:

The substituents in the given set are to be reordered from highest to lowest priority.

Concept introduction:

When assigning priorities to substituents, the atom having the greater atomic number has higher priority. In case of comparison between isotopes, the one having the greater atomic mass gets higher priority.

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Question: which of the following molecules will have the greatest difference in energy between its chair conformations? I understand that both B and D have chair conformations that are more favored one way than another (B because it's cis 1-3 where both substituents are equatorial or axial and D because for monosubstituents there are 1-3 diaxial interaction if the substituent is axial position) but why is B greater than D? Is it due to the fact it is two substituents over one? Can you explain this for me?
3. Rank the substituents in each of the following sets: (а) -Н, -ОН, -СH2CH3, -СH2CH2ОН (b) -СО2Н, -СО2CH3, -СH2ОН, -он (c) –CN, –CH2NH2, -CH2NHCH3, –NH2 (d) –SH, -CH2SCH3, –CH3, -SSCH3
e) How many asymmetric carbon atoms are present in the following compound? NHCH3 A) 0 B) 1| C) 2 D) 3 E) 4
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