(a) Interpretation: Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither. Concept introduction: A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

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Answer 1

Question

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

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Which of the following is not a constitutional isomer of the other three? NOTE: Correct Answer is not A or C.

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Answer 2

Question

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

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Answer 3

Question

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

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Answer 4

Question

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

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Answer 5

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 6

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 7

Chapter C, Problem C.12P

Interpretation Introduction

(a)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Considering only the IUPAC names, the given pairs of molecules are to be identified as enantiomers, diastereomers, or neither.

Concept introduction:

A pair of configurational isomers can be identified as enantiomers or diastereomers on the basis of the R/S designation in the names of those molecules. If two stereoisomers have inverse configuration at each corresponding chiral center, they are enantiomers of each other. If two stereoisomers have inverse configuration at some, but not all corresponding chiral centers, they are diastereomers of each other.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. C - Prob. C.1P Ch. C - Prob. C.2P Ch. C - Prob. C.3P Ch. C - Prob. C.4P Ch. C - Prob. C.5P Ch. C - Prob. C.6P Ch. C - Prob. C.7P Ch. C - Prob. C.8P Ch. C - Prob. C.9P Ch. C - Prob. C.10P

Solution Summary: The author explains that the given pair of molecules are enantiomers due to opposite configuration at each chiral center.

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