How much heat in kilojoules is evolved or absorbed in the reaction of 1.00 g of Na with H 2 O ? Is the reaction exothermic or endothermic ? 2 N a ( s ) + 2 H 2 O ( l ) → 2 N a O H ( a q ) + H 2 ( g ) Δ H ° = − 368. 4 kJ
How much heat in kilojoules is evolved or absorbed in the reaction of 1.00 g of Na with H 2 O ? Is the reaction exothermic or endothermic ? 2 N a ( s ) + 2 H 2 O ( l ) → 2 N a O H ( a q ) + H 2 ( g ) Δ H ° = − 368. 4 kJ
Solution Summary: The author explains that the amount of heat evolved or absorbed in the reaction of sodium and water needs to be determined.
How much heat in kilojoules is evolved or absorbed in the reaction of 1.00 g of Na with
H
2
O
? Is the reaction exothermic or endothermic ?
2
N
a
(
s
)
+
2
H
2
O
(
l
)
→
2
N
a
O
H
(
a
q
)
+
H
2
(
g
)
Δ
H
°
=
−
368.
4 kJ
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Statifically more chances to abstract one of these 6H
11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
4th total
• 6H total
래
• 4H total
21 total
ZH
2H
Statistical
H < 3° C-H weakest
-
product
abstraction here
bund
leads to thermo favored
a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
II
HA
H
CH3O-H
H
①
Do the Lone Pairs get added bc its valence e's are a total of 6 for oxygen and that completes it or due to other reasons. How do we know the particular indication of such.
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