Concept explainers
Fill in the missing product in each acid-base equation.
a.
b.
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General, Organic, & Biological Chemistry
- In each of the following acid-base reactions, identify the Brnsted acid and base on the left and their conjugate partners on the right. (a) C2H5N(aq) + CH3CO2H(aq) C5H5NH+(aq) + CH3CO2(aq) (b) N2H4(aq) + HSO4(aq) N2H5+(aq) + SO42(aq) (c) [Al(H2O)6]3+ (aq) + OH(aq) [Al(H2O)5OH]2+ (aq) + H2O+()arrow_forward8-15 Write an equation for the reaction that takes place when each base is added to water. (a) LiOH (b) (CH3)2NH (c) Sr(OH)2 (d) CH3CH2NH2arrow_forwardSketch two graphs: (a) percent dissociation for weak acid HA versus the initial concentration of HA ([HA]0) and(b) H+ concentration versus [HA]0. Explain both.arrow_forward
- Which of the following compounds or ions has the weakest conjugate base? Briefly explain your choice. a) HCN b) HClO c) NH4+arrow_forwardAre solutions of the following salts acidic, basic, or neutral? For those that are not neutral, write balanced equations for the reactions causing the solution to be acidic or basic. The relevant Ka, and Kb values are found in Tables 13-2 and 13-3. a. Sr(NO3)2 b. NH4C2H3O2 c. CH3NH3Cl d. C6H5NH3ClO2 e. NH4F f. CH3NH3CNarrow_forward12.63 For each of the following reactions, indicate the Bronsted-Lowrv acids and bases. What are the conjugate acid-base pairs? CN’(aq) + H2O(€) «=* HCN(aq) + OH’(aq) HCO}-(aq) + H,o+(aq) +* H2CO,(aq) + H,O(€) (C) CH,CtX)H(aq) + HS~(aq)i=i CH}COO"(aq) + H2S(aq)arrow_forward
- A solution contains a mixture of acids: 0.50 M HA (Ka = 1 103), 0.20 M HB (Ka = 1.0 1010), and 0.10 M HC (Ka = 1.0 1012). Calculate the [H] in this solution.arrow_forwardA solution of formic acid (HCOOH, Ka = 1.8 104) has a pH of 2.70. Calculate the initial concentration of formic acid in this solution.arrow_forwardCalculate the pKa value for each of the following acids. a. Phosphoric acid (H3PO4), Ka = 7.5 103 b. Hydrofluoric acid (HF), Ka = 6.8 104 c. Hydrogen phosphate ion (HPO42), Ka = 4.2 1013 d. Propanoic acid (HC3H5O2), Ka = 1.3 105arrow_forward
- What is the conjugate acid of each of the following? What is the conjugate base of each?. (a) OH-. (b) H2O. (c) HCO3-. (d) NH3. (e) HSO4-. (f) H2O2. (g) HS-. (h) H5N2+arrow_forwardExplain the difference between a strong acid and a weak acid.arrow_forwardSalicylic acid, HOC6H4CO2H, and its derivatives have been used as pain relievers for a long time. Salicylic acid occurs in small amounts in the leaves, bark, and roots of some vegetation (most notably historically in the bark of the willow tree). Extracts of these plants have been used as medications for centuries. The acid was first isolated in the laboratory in 1838. (a) Bath functional groups of salicylic acid ionize in water, with Ka=1.0103 for the—CO2H group and 4.201013 for the -OH group. What is the pH of a saturated solution of the acid (solubility = 1.8 g/L).. (b) Aspirin was discovered as a result of efforts to produce a derivative of salicylic acid that would not be irritating to the stomach lining. Aspirin is acetylsalicylic acid, CH3CO2C6H4CO2H. The -CO2H functional group is still present, but its acidity is reduced, Ka=3.0104. What is the pH of a solution of aspirin with the same concentration as a saturated solution of salicylic acid (See Part a). (c) Under some conditions, aspirin reacts with water and forms a solution of salicylic acid and acetic acid: CH3CO2C6H4CO2H(aq)+H2O(l)HOC6H4CO2H(aq)+CH3CO2H(aq) i. Which of the acids, salicylic acid or acetic acid, produces more hydronium ions in such a solution? ii. What are the concentrations of molecules and ions in a solution produced by the hydrolysis of 0.50 g of aspirin dissolved in enough water to give 75 mL of solution?arrow_forward
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