Organic Chemistry: Structure and Function
Organic Chemistry: Structure and Function
8th Edition
ISBN: 9781319079451
Author: K. Peter C. Vollhardt, Neil E. Schore
Publisher: W. H. Freeman
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Chapter 9, Problem 66P

(a)

Interpretation Introduction

Interpretation: The stronger acid and stronger base from CH3SH and CH3OH needs to be determined.

Concept Introduction: A compound is said to be acidic in nature if it can donate a proton or accept electrons. Similarly, a compound that can easily donate electrons and accept protons (hydrogen ion/s) is a base.

(b)

Interpretation Introduction

Interpretation: The stronger acid and stronger base from HS and HO needs to be determined.

Concept Introduction: A compound is said to be acidic in nature if it can donate a proton or accept electrons. Similarly, a compound that can easily donate electrons and accept protons (hydrogen ion/s) is a base.

(c)

Interpretation Introduction

Interpretation: The stronger acid and stronger base from H3S+ and H2S needs to be determined.

Concept Introduction: A compound is said to be acidic in nature if it can donate a proton or accept electrons. Similarly, a compound that can easily donate electrons and accept protons (hydrogen ion/s) is a base.

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3. For the following acid - base reaction, (a) predict the products; (b) identify the Bronsted acid, Bronsted base, conjugate acid, and conjugate base; (c) use curved arrows to show the flow of electron pairs in the reaction. CH3 CH2C-OH + NaNHa
(a) Predict the products of the following acid-base reactions using curved-arrow mechanisms to indicate electron flow. (b) Indicate the acid, base, conjugate acid, and conjugate base of each reaction. (c) Indicate whether the reactants or products are favored at equilibrium a) CH,COOH CH3O b) CH,CH,OH H2N
F3C - T SOH Br3C III Rank the compounds (shown below) in order of increasing acidity. H3C ОН II ОН A) | < ||| < || B) ||| < || < | C) || < III < | D) ||| < | < || E) II < I < |||

Chapter 9 Solutions

Organic Chemistry: Structure and Function

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