PHYSICAL SCIENCE (LCPO)
PHYSICAL SCIENCE (LCPO)
12th Edition
ISBN: 9781265774660
Author: Tillery
Publisher: MCG
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Chapter 9, Problem 4AC
To determine

The example of a monoatomic moleculeis:

O2

N2

Ar

O3

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3. Solid molecular hydrogen. For H₂ one finds from measurements on the gas that the Lennard-Jones parameters are & = 50×10-¹6 erg_and o = 2.96 Å. Find the cohesive energy in kJ per mole of H₂; do the calculation for an fcc structure. Treat each H₂ molecule as a sphere. The observed value of the cohesive energy is 0.751 kJ/mol., much less than we calculated, so that quantum corrections must be very important.
1. How do molecular mechanical methods calculate the potential energies of molecules?
For this question there could be one or MULTIPLE answers, Choose the best Match/Matches. For a monatomic ideal gas in thermal equilibrium near room temperature,   a. U = 3/2 NkT.   b. U = 5/2 NkT.   c. degrees of freedom include translational and rotational motions.   d. degrees of freedom include translational, rotational, and vibrational motions.   e. U = 5/2 pV.   f. U = 3/2 pV. Explain work please.

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PHYSICAL SCIENCE (LCPO)

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