Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
13th Edition
ISBN: 9780134421353
Author: Karen C. Timberlake
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 19CI
Tamiflu (oseltamivir), C16H28N2O4, is an antiviral drug used to treat influenza. The preparation of Tamiflu begins with the extraction of shikimic acid from the seedpods of star anise. From 2.6 g of star anise,0.13 g of shikimic acid can be obtained and used to produce one capsule containing 75 mg of Tamiflu.The usual adult dosage for treatment of influenza is two capsule of Tamiflu daily for 5 days. (7.1, 7.2)
- If black spheres are carbon atoms, white spheres are hydrogen atoms, and red spheres are oxygen atoms, what is the formula of shikimic acid?
- What is the moral mass of shikimic acid?
- How many moles of shikimic acid are contained in 130 g of shikimic acid?
- How many capsules containing 75 mg of Tamiflu could be produced from 155 g of star anise?
- What is the moral mass of Tamiflu?
- How many kilograms of Tamiflu would be needed to treat all the people in a city with a population of 500 000 if each person consumes two Tamiflu capsules a day for 5 days?
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Aspirin (acetylsalicylic acid, C9H8O4) is made by reacting salicylic acid (C7H6O3) with acetic anhydride [(CH3CO)2O]:
C7H6O3(s)+ (CH3CO)2O(l) → C9H8O4(s) + CH3COOH(l) In one preparation, 3.077 g of salicylic acid and 5.50 mL of acetic anhydride react to form 3.281 g of aspirin. (a) Which is the limiting reactant (d of acetic anhydride = 1.080 g/mL)? (b) What is the percent yield of this reaction? (c) What is the percent atom economy of this reaction?
Aspirin (acetylsalicylic acid, C9H8O4) is made by reacting salicylic acid (C7H6O3) with acetic anhydride [(CH3CO)2O]: C7H6O3(s) + (CH3CO)2O(l) → C9H8O4(s) + CH3COOH(l)In one preparation, 3.077 g of salicylic acid and 5.50 mL of aceticanhydride react to form 3.281 g of aspirin. (a) Which is the limitlimiting reactant (d of acetic anhydride = 1.080 g/mL)? (b) What is the percent yield of this reaction?
Given the balanced reaction between salicylic acid (C7H6O3) and acetic anhydride (C4H6O3) to produce ASA or acetylsalicylic acid (C9H8O4) and acetic acid (C2H4O2), the following experimental materials are provided: 5.00 g of pure salicylic acid, 7.14 g of acetic anhydride and 8 drops concentrated sulfuric acid as catalyst. After successful synthesis, the group was able to collect 5.25 grams of acetylsalicylic acid. (Atomic weight: C = 12 amu; H = 1 amu; O = 16 amu; density acetic anhydride = 1.08 g/mL).
a. How much of the EXCESS reagent is left unused after the reaction?
b. What is the PERCENTAGE in the experiment?
c. What is the THEORETICAL yield of ASA in the experiment?
Chapter 9 Solutions
Chemistry: An Introduction to General, Organic, and Biological Chemistry (13th Edition)
Ch. 9.1 - Prob. 9.1PPCh. 9.1 - Prob. 9.2PPCh. 9.1 - Describe the formation of an aqueous KI solution,...Ch. 9.1 - Describe the formation of an aqueous LiBr...Ch. 9.1 - Prob. 9.5PPCh. 9.1 - Water is a polar solvent and hexane (C6H12)is a...Ch. 9.2 - Prob. 9.7PPCh. 9.2 - NaOHis a strong electrolyte, and CH3OH is a...Ch. 9.2 - Write a balanced equation for the dissociation of...Ch. 9.2 - Write the balanced equation for the dissociation...
Ch. 9.2 - Indicate whether aqueous solutions of each of the...Ch. 9.2 - Prob. 9.12PPCh. 9.2 - Prob. 9.13PPCh. 9.2 - Prob. 9.14PPCh. 9.2 - Calculate the number of equivalents in each of the...Ch. 9.2 - Calculate the number of equivalents in each of the...Ch. 9.2 - An intravenous saline solution contains 154 mEq/L...Ch. 9.2 - An intravenous solution to replace potassium loss...Ch. 9.2 - Prob. 9.19PPCh. 9.2 - A Ringer's solutioncontains the following...Ch. 9.2 - When Michael's blood was tested, the chloride...Ch. 9.2 - After dialysis, the level of magnesium in...Ch. 9.3 - State whether each of the following refers to a...Ch. 9.3 - State whether each of the following refers to a...Ch. 9.3 - Determine whether each of the following solutions...Ch. 9.3 - Determine whether each of the following solutions...Ch. 9.3 - A solution containing 80. g of KClin 200 g of H2O...Ch. 9.3 - A solution containing 80. g of NaNO3 in 75 g of...Ch. 9.3 - Explain the following observations More sugar...Ch. 9.3 - Explain the following observations: And open can...Ch. 9.3 - Predict whether each of the following organic...Ch. 9.3 - Predict whether each of the following organic...Ch. 9.4 - Calculate the mass percent (m/m) for the solute in...Ch. 9.4 - Calculate the mass percent (m/m) for the solute in...Ch. 9.4 - A mouthwash contains 22.5% (v/v) alcohol.If the...Ch. 9.4 - A bottle of champagne is 11% (v/v) alcohol. If...Ch. 9.4 - What is the difference between a 5.0% (m/m)...Ch. 9.4 - What is the difference between a 10.0% (v/v)...Ch. 9.4 - Calculate the mass/volume(m/v) percent for the...Ch. 9.4 - Calculate the mass/volume (m/v) percent for the...Ch. 9.4 - Calculate the grams or milliliters of solute...Ch. 9.4 - Calculate the grams or ml of solute needed to...Ch. 9.4 - Prob. 9.43PPCh. 9.4 - For each of the following solutions, calculate...Ch. 9.4 - Prob. 9.45PPCh. 9.4 - Prob. 9.46PPCh. 9.4 - Calculate the gram of solely needed to prepare...Ch. 9.4 - Calculate the gram of solute needed to prepare...Ch. 9.4 - For each of the following solutions, calculate...Ch. 9.4 - Prob. 9.50PPCh. 9.4 - A patient received 100 mL of a 20.0% (m/v)...Ch. 9.4 - A patient received 250 mL of a 4.0% (m/v) amino...Ch. 9.4 - A patient needs 100. g of glucose in the next 12...Ch. 9.4 - A patient received 2.0 g of NaCl in 8 h. How many...Ch. 9.5 - Prob. 9.55PPCh. 9.5 - Prob. 9.56PPCh. 9.5 - Determine the final volume, in milliliters, of...Ch. 9.5 - Prob. 9.58PPCh. 9.5 - Prob. 9.59PPCh. 9.5 - Prob. 9.60PPCh. 9.5 - You need 500. mL of a 5.0% (m/v) glucose solution....Ch. 9.5 - A doctor ordered 100. mL of 2.0% (m/v)...Ch. 9.6 - Prob. 9.63PPCh. 9.6 - Identify each of the following as characteristics...Ch. 9.6 - A 10% (m/v) starch solution is separated form a 1%...Ch. 9.6 - A 0.1% (m/v) albumin solution is separated form a...Ch. 9.6 - Indicate the compartment (A or B) that will...Ch. 9.6 - Indicate the compartment (A or B) that will...Ch. 9.6 - Will a red blood cell undergo creation, hemolysis,...Ch. 9.6 - Will a red blood cell undergo creation, hemolysis,...Ch. 9.6 - Each of the following mixtures is placed in a...Ch. 9.6 - Prob. 9.72PPCh. 9.6 - 9.73 After her latest dialysis treatment, Michael...Ch. 9.6 - Prob. 9.74PPCh. 9.6 - 9.75 A CaCl2solution is given to increase blood...Ch. 9.6 - 9.76 10 intravenous solution of mannitol is used...Ch. 9 - Prob. 9.77UTCCh. 9 - Prob. 9.78UTCCh. 9 - Prob. 9.79UTCCh. 9 - Prob. 9.80UTCCh. 9 - Prob. 9.81UTCCh. 9 - Whydo lettuces leaves in a salad with after a...Ch. 9 - Prob. 9.83UTCCh. 9 - Prob. 9.84UTCCh. 9 - Prob. 9.85APPCh. 9 - Prob. 9.86APPCh. 9 - Prob. 9.87APPCh. 9 - Prob. 9.88APPCh. 9 - Prob. 9.89APPCh. 9 - Prob. 9.90APPCh. 9 - Prob. 9.91APPCh. 9 - Prob. 9.92APPCh. 9 - Prob. 9.93APPCh. 9 - Prob. 9.94APPCh. 9 - Prob. 9.95APPCh. 9 - Prob. 9.96APPCh. 9 - Prob. 9.97APPCh. 9 - Prob. 9.98APPCh. 9 - Prob. 9.99APPCh. 9 - Prob. 9.100APPCh. 9 - Prob. 9.101APPCh. 9 - Prob. 9.102APPCh. 9 - Prob. 9.103APPCh. 9 - Prob. 9.104APPCh. 9 - Prob. 9.105APPCh. 9 - Prob. 9.106APPCh. 9 - Calculate the final concentration of the solution...Ch. 9 - Calculate the final concentration of the solution...Ch. 9 - Prob. 9.109APPCh. 9 - Prob. 9.110APPCh. 9 - Prob. 9.111APPCh. 9 - Prob. 9.112APPCh. 9 - Prob. 9.113CPCh. 9 - 9.114. In a laboratory experiment, a 15.0-sample...Ch. 9 - Prob. 9.115CPCh. 9 - Prob. 9.116CPCh. 9 - Prob. 9.117CPCh. 9 - Prob. 9.118CPCh. 9 - Prob. 13CICh. 9 - Automobile exhaust is a major cause of air...Ch. 9 - Bleach is often added to a wash to remove stains...Ch. 9 - The compound butyric acid gives rancid butter its...Ch. 9 - Methane is a major component of purified natural...Ch. 9 - The active ingredient in Turns is calcium...Ch. 9 - Tamiflu (oseltamivir), C16H28N2O4, is an antiviral...Ch. 9 - Prob. 20CI
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