Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Textbook Question
Chapter 8.15C, Problem 8.37P
Predict the major products of the following reactions.
- a. (E)-3-methyloct-3-ene + ozone, then (CH3)2 S
- b. (Z)-3- methyloct -3-ene + warm, concentrated KMnO4
- c. 1- ethylcycloheptene + ozone, then (CH3)2 S
- d. 1ethylcycloheptene + warm, concentrated KMnO4
- e. 1- ethylcycloheptene + cold, dilute KMnO4
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8
Is this molecule E or Z. Ne
Attachments
HOCH₂ CH₂CH₂Cl
CH3CH2
CH₂CI
A. Z
B. E
What is the complete name of the molecule below, if the base name of the
molecule is 3-bromo-5-isopropylcyclohexene? Ne
Attachments.
Br
A. (3,S)-bromo-(5,R)-isopropyl-E-cyclohexene
B. (3,S)-bromo-(5,R)-isopropyl-Z-cyclohexene
C. (3,R)-bromo-(5,R)-isopropyl-Z-cyclohexene
D. (3,S)-bromo-(5,S)-isopropyl-Z-cyclohexene
2. Predict the product(s) of the following reactions. If more than one product is expected, indicate
major and minor ones.
(CH,),CONO
- NH,
DMF, 65°C
а.
H,SO, H,0
CH,
-So,H
HgSO,
b.
18-crown-6
CN +F
KOAC
с.
[References]
From the choices provided below, list the reagent(s) in order that will yield the following transformation.
a. HIO
Br
H
Reagents available
1. H2SO4, H₂O
b. HC=C Na
j. potassium tert-butoxide
c. CH3O Na+, CH3OH k. RCO₂H
d. NaCN
1. HN(CH2CH3)2
e. CH3CH2S Na+
m. NBS, hv
f. H₂O+
n. OsO4, H2O2
9. H₂O
o. NaOH
h. H₂ CrO4
p. pyridinium chlorochromate
(PCC)
H
List your answer as a series of letters in the order the reagents are used (with no commas separating them). No more than four steps are required for this synthesis. Use the
minimum number of steps possible. Reagents may be used more than once in subsequent steps. For example, "dop". Note: The order in which you list your letters matters!
Your answer:
Chapter 8 Solutions
Organic Chemistry (9th Edition)
Ch. 8.3A - Predict the major products of the following...Ch. 8.3A - a. When 1 mole of buta-1,3-diene reacts with 1...Ch. 8.3B - Predict the major products of the following...Ch. 8.3B - Show how you would accomplish the following...Ch. 8.4B - Propose a mechanism to show how...Ch. 8.4B - Predict the products of the following hydration...Ch. 8.6 - a. Propose a mochansm fortho following reaction....Ch. 8.6 - Prob. 8.8PCh. 8.6 - Prob. 8.9PCh. 8.7A - Prob. 8.10P
Ch. 8.7A - Prob. 8.11PCh. 8.7C - Prob. 8.12PCh. 8.7C - Prob. 8.13PCh. 8.7C - a. When (Z)-3-methylhex-3-ene undergoes...Ch. 8.7C - Prob. 8.15PCh. 8.7C - Prob. 8.16PCh. 8.8B - Prob. 8.17PCh. 8.8B - Prob. 8.18PCh. 8.9 - Prob. 8.19PCh. 8.9 - Prob. 8.20PCh. 8.9 - Prob. 8.21PCh. 8.9 - Prob. 8.22PCh. 8.10 - Prob. 8.23PCh. 8.10 - Prob. 8.24PCh. 8.10 - Prob. 8.25PCh. 8.11A - Prob. 8.26PCh. 8.11B - Prob. 8.27PCh. 8.11B - Prob. 8.28PCh. 8.12 - Prob. 8.29PCh. 8.13 - a. Propose a mechanism for the conversion of...Ch. 8.13 - Magnesium monoperoxyphthalate (MMPP) epoxidizes...Ch. 8.13 - Predict the major products of the following...Ch. 8.13 - When 1,2-epoxycyclohexane (cyclohexene oxide) is...Ch. 8.14C - Predict the major products of the following...Ch. 8.14C - Prob. 8.35PCh. 8.15B - Prob. 8.36PCh. 8.15C - Predict the major products of the following...Ch. 8.16A - Prob. 8.38PCh. 8.16A - Prob. 8.39PCh. 8.16B - Prob. 8.40PCh. 8.16B - Prob. 8.41PCh. 8.16C - Prob. 8.42PCh. 8.17B - Prob. 8.43PCh. 8.17B - Prob. 8.44PCh. 8.17B - Show how you would synthesize each compound,...Ch. 8 - Prob. 8.46SPCh. 8 - Prob. 8.47SPCh. 8 - Give the products expected when the following...Ch. 8 - Show how you would make the following compounds...Ch. 8 - Using 1,2-dimethylcyclohexene as your starting...Ch. 8 - Show how you would synthesize each compound using...Ch. 8 - Prob. 8.52SPCh. 8 - Show how you might use olefin metathesis to...Ch. 8 - Prob. 8.54SPCh. 8 - Prob. 8.55SPCh. 8 - Propose mechanisms consistent with the following...Ch. 8 - Prob. 8.57SPCh. 8 - Prob. 8.58SPCh. 8 - Draw a reaction-energy diagram for the propagation...Ch. 8 - Prob. 8.60SPCh. 8 - Prob. 8.61SPCh. 8 - Prob. 8.62SPCh. 8 - Prob. 8.63SPCh. 8 - Prob. 8.64SPCh. 8 - Prob. 8.65SPCh. 8 - Prob. 8.66SPCh. 8 - Prob. 8.67SPCh. 8 - Prob. 8.68SPCh. 8 - Prob. 8.69SPCh. 8 - Prob. 8.70SPCh. 8 - Prob. 8.71SPCh. 8 - Prob. 8.72SPCh. 8 - Prob. 8.73SPCh. 8 - Prob. 8.74SPCh. 8 - Prob. 8.75SPCh. 8 - Prob. 8.76SPCh. 8 - Prob. 8.77SPCh. 8 - Prob. 8.78SPCh. 8 - Prob. 8.79SP
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