EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
expand_more
expand_more
format_list_bulleted
Question
Chapter 8, Problem 8.17YT
Interpretation Introduction
Interpretation:
The step that makes the given mechanism unreasonable is to be labeled and explained.
Concept introduction:
Under the acidic condition, strong basic intermediate or a species is not compatible because the proton transfer reaction between acid proton and the base
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Chloromethane reacts with dilute sodium cyanide (Na+ -C‚N) chloromethane cyanide acetonitrile chloride. When the concentration of chloromethane is doubled, the rate is observed to double. When the concentration of cyanide ion is tripled, the rate is observed to triple. Write the rate equation for this reaction.
1-Bromobutane reacts with water to form 1-butanol according to the following equation.
C4H,Br(aq) + 2 H20(1) → C¿H,OH(aq) + H30*(aq) + Br¯(aq)
The following is a proposed mechanism for the reaction.
C4H9B1(aq) → C4H,*(aq) + Br¯(aq)
C4H,*(aq) + H,0(1) → C4H3OH,*(aq)
C,H,OH,*(aq) + H,0() – CH,OH(aq) + H30*(aq)
slow
fast
fast
Determine the overall rate law for this proposed mechanism. (Rate expressions take the general form: rate = k. [A]ª . [B]°.)
chemPad
Help
Greek -
Rate=k[C4H9B1][H2o²]
Rate=k[C_4H_9Br][H_2O^2]
Remember that answers are case-sensitive. Your answer contains an incorrect or incomplete chemical formula.
Please
Chapter 8 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 8 - Prob. 8.1PCh. 8 - Prob. 8.2PCh. 8 - Prob. 8.3PCh. 8 - Prob. 8.4PCh. 8 - Prob. 8.5PCh. 8 - Prob. 8.6PCh. 8 - Prob. 8.7PCh. 8 - Prob. 8.8PCh. 8 - Prob. 8.9PCh. 8 - Prob. 8.10P
Ch. 8 - Prob. 8.11PCh. 8 - Prob. 8.12PCh. 8 - Prob. 8.13PCh. 8 - Prob. 8.14PCh. 8 - Prob. 8.15PCh. 8 - Prob. 8.16PCh. 8 - Prob. 8.17PCh. 8 - Prob. 8.18PCh. 8 - Prob. 8.19PCh. 8 - Prob. 8.20PCh. 8 - Prob. 8.21PCh. 8 - Prob. 8.22PCh. 8 - Prob. 8.23PCh. 8 - Prob. 8.24PCh. 8 - Prob. 8.25PCh. 8 - Prob. 8.26PCh. 8 - Prob. 8.27PCh. 8 - Prob. 8.28PCh. 8 - Prob. 8.29PCh. 8 - Prob. 8.30PCh. 8 - Prob. 8.31PCh. 8 - Prob. 8.32PCh. 8 - Prob. 8.33PCh. 8 - Prob. 8.34PCh. 8 - Prob. 8.35PCh. 8 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Prob. 8.41PCh. 8 - Prob. 8.42PCh. 8 - Prob. 8.43PCh. 8 - Prob. 8.44PCh. 8 - Prob. 8.45PCh. 8 - Prob. 8.46PCh. 8 - Prob. 8.47PCh. 8 - Prob. 8.48PCh. 8 - Prob. 8.49PCh. 8 - Prob. 8.50PCh. 8 - Prob. 8.51PCh. 8 - Prob. 8.52PCh. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Prob. 8.55PCh. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - Prob. 8.64PCh. 8 - Prob. 8.65PCh. 8 - Prob. 8.66PCh. 8 - Prob. 8.67PCh. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - Prob. 8.75PCh. 8 - Prob. 8.76PCh. 8 - Prob. 8.1YTCh. 8 - Prob. 8.2YTCh. 8 - Prob. 8.3YTCh. 8 - Prob. 8.4YTCh. 8 - Prob. 8.5YTCh. 8 - Prob. 8.6YTCh. 8 - Prob. 8.7YTCh. 8 - Prob. 8.8YTCh. 8 - Prob. 8.9YTCh. 8 - Prob. 8.10YTCh. 8 - Prob. 8.11YTCh. 8 - Prob. 8.12YTCh. 8 - Prob. 8.13YTCh. 8 - Prob. 8.14YTCh. 8 - Prob. 8.15YTCh. 8 - Prob. 8.16YTCh. 8 - Prob. 8.17YTCh. 8 - Prob. 8.18YTCh. 8 - Prob. 8.19YT
Knowledge Booster
Similar questions
- d) During the reaction between 3, 3-dimethylbutene (W) and HBr, intermediate species and Y are formed. CH3 CH;-C-CH=CH2 ČH3 HBr Y step 1 step 2 step 3 i) Write a mechanism for the formation of intermediate X? ii) Write the structure of intermediate Y? iii) Explain in your own words what happens in step 2 of the reaction? iv) Write a mechanism for the formation of Z from Y?arrow_forwardThe following molecule has been formed by combining ketone and KCN (cyanohydrin) Sketch a skeletal formula for this reaction and using the curly arrow notation, give the reaction mechanism for this reaction.arrow_forwardWrite the step by step mechanism for the following reactionarrow_forward
- The following compounds are major products of an elimination reaction with an alkyl halide. Determine the structure of the alkyl halide and write the overall reaction mechanism.arrow_forward7arrow_forwardAccount for the relationship between the rate of a reaction and its activation energy, and the relationship between the rate of the reaction and the reaction temperature. Group of answer choices The rate of reaction will increase as the activation energy decreases; the rate of reaction will increase as the reaction temperature increases. The rate of reaction will increase as the activation energy decreases; the rate of reaction will remain the same as the reaction temperature increases. The rate of reaction will increase as the activation energy increases; the rate of reaction will increase as the reaction temperature increases. The rate of reaction will remain the same as the activation energy decreases; the rate of reaction will increase as the reaction temperature increases. The rate of reaction will increase as the activation energy decreases; the rate of reaction will decrease as the reaction temperature increases.arrow_forward
- Question Completion Status: 10 3 6 10 12 13 470 480 49D 500 11 140 39 40 41 440 450 15 16 17 18 42 43 46 19 20 21 22 23 24 25 QUESTION 42 In the formal SN1 mechanism, the reaction has two steps; however, in reality steps are actually needed to produce the final product. 03 O 2 0 1 QUESTION 43 The reactive intermediate in the SN1 reaction of 3-ethyl-2-bromo-hexane in methanol will spontaneously rearrange to become a reactive intermediate. O benzylic O secondary O tertiary O allylic O primary QUESTION 44 The reaction of 1-chloropropane with which of the following nucleophiles is a carbon chain-lengthening reaction? O ammonia O sodium hydroxide O potassium acetylide O sodium iodide tert-butoxidearrow_forwardproduct obtained and draw the mechanism of its formation. Draw all missing reactants and/or products in the appropriate boxes by placing atoms on the canvas and connecting them with bonds. Add charges w arrows should start on the electron(s) of an atom or a bond and should end on an atom, bond, or location where a new bond should be created. DDC H EXP CONT ? L W OH H―CI: A ΔΟ CE CI :CI: H―CIAarrow_forward(asap within 30 min plzarrow_forward
- The reaction of ozone with 2-butene leads to -10 formation of aldehyde + O ketones, aldehyde + alcohol, two molecules of carboxylic acid O.arrow_forwardActivated complex 200 (a) 150 Potential Reactants (b) Energy 100 (c) Products 50 Reaction Pathway Nina claims that the graph shown above represents an exothermic reaction with a AH of +100kJ and that energy will be absorbed during this reaction. Is Nina correct? If not, explain and correct her mistake giving explanation. Format BIU- a Farcharrow_forwardThe decomposition of di-2-methylpropan-2-yl peroxide produces propanone and ethane: (CH3)3COOC(CH3)3 → 2CH3COCH3 + C₂H6 and is described by the generally accepted mechanism: (CH3)3COOC(CH3)3 → 2 (CH3)3CO (CH3)3CO → CH3COCH3 + CH3* CH3 + CH3 →→ C₂H6 k₁ k₂ k3 1. Identify the intermediates. 2. Explain why this is NOT a chain reaction. 3. Confirm using the steady state approximation that the production of ethane is first order even though it takes place in a number of steps.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:Cengage Learning