(A)
Interpretation:
Find the molar volume using Soave’s EOS.
Concept Introduction:
Write the relationship between the parameter, m and Soave’s EOS.
Here, the acentric factor is
Write the expression to calculate the
Here, reduced temperature is
Write the expression to calculate the reduced temperature.
Here, critical temperature is
Write the expression to calculate the value of a at the critical point.
Write the expression to calculate the value of b using the Soave equation.
Write the expression to calculate the molar volume using the Soave equation.
Here, system pressure is P.
(B)
Interpretation:
Find the molar volume using Peng Robinson EOS.
Concept Introduction:
Write the expression to calculate the parameter a for Peng-Robinson EOS.
Write the expression to calculate the
Write the expression to calculate the value of parameter a at the critical point.
Write the expression to calculate the van der Waals parameter
Write the expression to calculate the van der Waals parameter
Write the expression to calculate the molar volume
(C)
Interpretation:
Find the molar volume using virial EOS.
Concept Introduction:
Write the expression to calculate the virial parameter or coefficient
Write the expression to calculate the virial parameter
Write the expression to calculate parameter as a function of temperature and the acentric factor.
Here, function of temperature is
Write the expression to calculate the relative pressure.
Write the expression to calculate the virial compressibility factor
(D)
Interpretation:
Find the molar volume using Lee-Kesler equation.
Concept Introduction:
Write the expression to calculate the compressibility factor
Here, compressibility of compound with
(E)
Interpretation:
Find the molar volume using Appendix F.
Concept Introduction:
Write the expression to calculate the molar volume.
Here, specific volume is
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