Organic Chemistry (9th Edition)
Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 7.13, Problem 7.25P

(a)

Interpretation Introduction

To determine: The products of the reaction of 1-bromo-1-methycyclohexane in a solution of sodium hydroxide in acetone and the type of the reaction.

Interpretation: The products of the reaction of 1-bromo-methycyclohexane in a solution of sodium hydroxide in acetone are to be determined and the type of the reaction is to be identified.

Concept introduction: The SN1 reaction is the mechanism of nucleophilic substitution reaction that occurs in two steps. In SN2 reaction, the nucleophilic substitution reaction occurs in which one of the bonds is broken and simultaneously another bond is formed.

According to the Zaitsev rule, the formation of alkene occurs by the elimination of the hydrogen from the carbon that has less number of hydrogen.

(b)

Interpretation Introduction

To determine: The products of the reaction of 1-bromo-1-methycyclohexane with triethylamine and the type of the reaction.

Interpretation: The products of the reaction of 1-bromo-methycyclohexane with triethylamine are to be determined and the type of the reaction is to be identified.

Concept introduction: The SN1 reaction is the mechanism of nucleophilic substitution reaction that occurs in two steps. In SN2 reaction, the nucleophilic substitution reaction occurs in which one of the bonds is broken and simultaneously another bond is formed.

According to the Zaitsev rule, the formation of alkene occurs by the elimination of the hydrogen from the carbon that has less number of hydrogen.

(c)

Interpretation Introduction

To determine: The products of the reaction of chlorocyclohexane with sodium methoxide in methanol and the type of the reaction.

Interpretation: The products of the reaction of chlorocyclohexane with sodium methoxide in methanol are to be determined and the type of the reaction is to be identified.

Concept introduction: The SN1 reaction is the mechanism of nucleophilic substitution reaction that occurs in two steps. In SN2 reaction, the nucleophilic substitution reaction occurs in which one of the bonds is broken and simultaneously another bond is formed.

According to the Zaitsev rule, the formation of alkene occurs by the elimination of the hydrogen from the carbon that has less number of hydrogen.

(d)

Interpretation Introduction

To determine: The products and the type of reactions occur between the given compounds.

Interpretation: The products and the type of reactions that occur between the given compounds are to be stated.

Concept introduction: In SN2 reaction, the nucleophilic substitution reaction occurs in which one of the bonds is broken and simultaneously another bond is formed.

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Chapter 7 Solutions

Organic Chemistry (9th Edition)

Ch. 7.8B - Use the data in Table7-2 to predict the energy...Ch. 7.8C - Prob. 7.13PCh. 7.8E - Explain why each of the following alkenes is...Ch. 7.8F - Prob. 7.15PCh. 7.10 - Prob. 7.16PCh. 7.10A - SN1 substitution and E1 elimination frequently...Ch. 7.10C - Prob. 7.18PCh. 7.10C - Prob. 7.19PCh. 7.10C - Prob. 7.20PCh. 7.11 - Prob. 7.21PCh. 7.11 - Prob. 7.22PCh. 7.12 - Prob. 7.23PCh. 7.12 - Prob. 7.24PCh. 7.13 - Prob. 7.25PCh. 7.14B - Prob. 7.26PCh. 7.14B - Make models of the blowing compounds, and predict...Ch. 7.15 - Prob. 7.28PCh. 7.15 - Prob. 7.29PCh. 7.15 - Prob. 7.30PCh. 7.15 - Prob. 7.31PCh. 7.16 - Predict the major and minor elimination products...Ch. 7.17B - Predict the products and mechanisms of the...Ch. 7.18 - Propose mechanisms for the following reactions.Ch. 7.18 - Prob. 7.35PCh. 7.19B - The dehydrogenation of butane to trans-but-2-ene...Ch. 7.19B - Prob. 7.37PCh. 7.19B - Prob. 7.38PCh. 7.19B - Prob. 7.39PCh. 7 - Prob. 7.40SPCh. 7 - Prob. 7.41SPCh. 7 - Prob. 7.42SPCh. 7 - Prob. 7.43SPCh. 7 - Prob. 7.44SPCh. 7 - Prob. 7.45SPCh. 7 - Prob. 7.46SPCh. 7 - The energy difference between cis- and...Ch. 7 - Prob. 7.48SPCh. 7 - Prob. 7.49SPCh. 7 - Prob. 7.50SPCh. 7 - What halides would undergo E2 dehydrohalogenation...Ch. 7 - Prob. 7.52SPCh. 7 - Prob. 7.53SPCh. 7 - Write a balanced equation for each reaction,...Ch. 7 - Prob. 7.55SPCh. 7 - Using cyclohexane as your starting material, show...Ch. 7 - Show how you would prepare cyclopentene from each...Ch. 7 - Prob. 7.58SPCh. 7 - E1 eliminations of alkyl halides are rarely useful...Ch. 7 - Prob. 7.60SPCh. 7 - Propose mechanisms for the following reactions....Ch. 7 - Prob. 7.62SPCh. 7 - Prob. 7.63SPCh. 7 - Prob. 7.64SPCh. 7 - Prob. 7.65SPCh. 7 - Prob. 7.66SPCh. 7 - Prob. 7.67SPCh. 7 - Prob. 7.68SPCh. 7 - Prob. 7.69SPCh. 7 - Explain the dramatic difference in rotational...Ch. 7 - One of the following dichloronorbornanes undergoes...Ch. 7 - A graduate student wanted to make...Ch. 7 - Prob. 7.73SPCh. 7 - Prob. 7.74SPCh. 7 - Prob. 7.75SPCh. 7 - Prob. 7.76SP
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