(a)
Interpretation:
The order with respect to each reactant and the overall order of the reaction have to be determined.
Concept Introduction:
The rate of the reaction is referred to the change in the molar concentration in the distinct interval of time. According to the rate law, the rate of the reaction is directly proportional to the initial concentration of the reactant of the reaction.
(a)
Answer to Problem 7A.15E
The order with respect to
Explanation of Solution
The given
Suppose the order of the reaction with respect to
Therefore, the generic rate law expression for the given chemical reaction is shown below.
Substitute the values of
Substitute the values of
Substitute the values of
Substitute the values of
Divide equation (2) and equation (5) to calculate the value of
Therefore, the order with respect to
Divide equation (2) and equation (3) to calculate the value of
Therefore, the order with respect to
Divide equation (2) and equation (4) to calculate the value of
Therefore, the order with respect to
Thus, the overall order of the reaction is
(b)
Interpretation:
The expression for the rate law has to be determined.
Concept Introduction:
Same as part (a).
(b)
Answer to Problem 7A.15E
The rate law for the given reaction,
Explanation of Solution
The order with respect to
Substitute the value of
Thus, the expression for rate law for the given chemical reaction is shown below.
(c)
Interpretation:
The rate constant for the given reaction has to be determined.
Concept Introduction:
Same as part (a).
(c)
Answer to Problem 7A.15E
The rate constant of the reaction is
Explanation of Solution
The expression for the rate law for the given reaction is shown below.
Substitute the value of
Thus, the rate constant of the reaction is
(d)
Interpretation:
The
Concept Introduction:
Same as part (a).
(d)
Answer to Problem 7A.15E
The reaction rate for the experiment 5 is
Explanation of Solution
Substitute the value of
Thus, the reaction rate for the experiment 5 is
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