The value of Δ G 0 for the biological synthesis of ammonia at 298 K should be calculated. Concept Introduction : For a general reaction as follows: Reactant → Product The value of change in Gibbs free energy of a reaction is calculated as follows: Δ G R = ∑ Δ G f ( Products) - ∑ Δ G f ( Reactants)

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Answer 1

Question

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

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Answer 2

Question

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Expert Solution & Answer

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Answer 3

Question

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Expert Solution & Answer

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Answer 4

Question

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Expert Solution & Answer

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Answer 5

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Answer 6

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

Answer 7

Chapter 6, Problem 6.15NP

(a)

Interpretation Introduction

Interpretation:

The value of ΔG0 for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

For a general reaction as follows:

Reactant→Product

The value of change in Gibbs free energy of a reaction is calculated as follows:

ΔGR=∑ΔGf(Products) - ∑ΔGf(Reactants)

Answer 8

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

Answer 9

(b)

Interpretation Introduction

Interpretation:

The equilibrium constant for the biological synthesis of ammonia at 298 K should be calculated.

Concept Introduction :

The change in Gibbs free energy of the reaction can be calculated from the equilibrium constant as follows:

ΔGR=−RTlnKP

Here,

ΔGR - Gibbes free energy changeR - universal gas constantT - temperatureKP- equilibrium constant

Answer 10

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 6 - Prob. 6.1CP Ch. 6 - Prob. 6.2CP Ch. 6 - Prob. 6.3CP Ch. 6 - Prob. 6.4CP Ch. 6 - Prob. 6.5CP Ch. 6 - Prob. 6.6CP Ch. 6 - Prob. 6.7CP Ch. 6 - Prob. 6.8CP Ch. 6 - Prob. 6.9CP Ch. 6 - Prob. 6.10CP

Interpretation: Whether the pathway is spontaneous should be determined. Concept Introduction : Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.

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Chapter 6 Solutions

Interpretation:

Whether the pathway is spontaneous should be determined.

Concept Introduction :

Spontaneity of a reaction can be predicted by the equilibrium constant. If KP <<1 forward reaction is not spontaneous. The backward reaction is favorable. If KP >>1 forward reaction is spontaneous.