Sketch the shape of each of the σ molecular orbitals for H2+ shown in Figure 6.5 in a plane perpendicular to the internuclear axis located at the midpoint between the two nuclei. Repeat the sketches for a plane perpendicular to the internuclear axis located at a point one quarter of the distance between the two nuclei. FIGURE 6.5 Wave functions for thefirst eight energy levels of the H;molecular ion, calculated exactly byquantum mechanics. The two nucleilie along the z-axis, which is in theplane of the paper. Regions ofpositive and negative amplitude areshown in red and blue, respectively.203oThe labels for each orbital areexplained in the text. The images areisosurfaces corresponding to contoursat + 0.1 of the maximum amplitude.The log is the ground state, and theenergies increase in the order lợg<1ot< 20g < 2ơở< 1ĩy< 3og< 1nž<3o. (Courtesy of Mr. Hatem Helal andProfessor William A. Goddand II, Califomia Institute ofTechnology, and Dr. Kelly P. Gaither, University of Texas atAustin.)20g1ng30g10g

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Sketch the shape of each of the σ molecular orbitals for H2+ shown in Figure 6.5 in a plane perpendicular to the internuclear axis located at the midpoint between the two nuclei. Repeat the sketches for a plane perpendicular to the internuclear axis located at a point one quarter of the distance between the two nuclei.

Sketch the shape of each of the σ molecular orbitals for H2+ shown in Figure 6.5 in a plane perpendicular to the internuclear axis located at the midpoint between the two nuclei. Repeat the sketches for a plane perpendicular to the internuclear axis located at a point one quarter of the distance between the two nuclei.

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 25P: Following the pattern of Figure 6.21, work out the correlation diagram for the CN molecule, showing...

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