
Concept explainers
You have a l.00-mole sample of water at −30.°C and you heat it until you have gaseous water at 140.°C. Calculate q for the entire process. Use the following data.
Specific heat capacity of ice=2.03 J/°C⋅gSpecific heat capacity of water=4.18 J/°C⋅gSpecific heat capacity of steam=2.02 J/°C⋅g
H2O(s)→H2O(l)ΔHfusion=6.02 KJ/mol (at 0°C)H2O(l)→H2O(g)ΔHvaporization=40.7 KJ/mol (at 100.°C)

Interpretation: The amount of heat required to convert 1.00 mol of H2O(s) at -30°C to H2O(g) at 140°C should be determined.
Concept Introduction:
The heat capacity C is defined as the relation of heat absorbed to the temperature change. It can be given by,
C = Heat absorbedTemperature change......(1)
Require heat for an one gram of substance raise to its temperature by one degree Celsius is called specific heat capacity.
Absorbed heat (J) = Specific heat capacity×Temperature change(c)×mass ofsubstance (g)......(2)
For the above equation heat is:
S = q×M×T.....(1)
q is heat (J)
M is mass of sample (g)
S is specific heat capacity (J/°C·g.)
T is temperature change (C)
For the process no heat loss to the surroundings means then the heat is
(absorbed)-q×M×ΔT=-q×M×ΔT (released)......(3)'
Answer to Problem 131CP
Answer
The amount of heat required to convert 1.00 mol of H2O(s) at -30°C to H2O(g) at 140°C is 56.9 kJ.
Explanation of Solution
Explanation
Record the given data:
Specific heat capacity of ice = 2.03J/°C· g
Specific heat capacity of water = 4.18 J/°C · g
Specific heat capacity of steam = 2.02J/°C· g
Sample water is l.00 mole
Initial temperature is - 30°C
Final temperature is - 140°C.
H2O(s) →H2O(l) ΔΗfusion= 6.02kJ/mol (at 0°C)H2O(l)→H2O(g) ΔΗvaporization= 40.7kJ/mol (at 100°C)
To calculate the required to heat H2O(s) from -30°C to 0°C.
q(1) = 2.30J°C.g×18.2g×(0-(-30))°C = 1.1 ×103 J
- The given values are plugging in equation (1) to give the required to heat H2O(s) from -30°C to 0°C.
- Required heat for vaporization of 1 mole of water is 1.1 ×103 J.
To calculate the required heat (q) to convert 1 mol H2O(s) at 0°C into 1 mol H2O(l) at 0°C.
q(1) = 1.00 mol ×6.02×103 J/mol = 6.02×103 J
- The given enthalpy of fusion is multiplied by the mole of water to give required heat (q) to convert 1 mol H2O(s) at 0°C into H2O(l) at 0°C.
- Required heat (q) to convert 1 mol H2O(s) at 0°C into H2O(l) at 0°C is 6.02×103 J.
To calculate the required to heat H2O(l) from 0°C to 100°C.
q(3) = 4.18J°C.g×18.2g×(100-0)°C = 7.53 ×103 J
- The given values are plugging in equation (1) to give the required to heat H2O(l) from 0°C to 100°C.
- Required to heat H2O(l) from 0°C to 100°C is 7.53 ×103 J.
To calculate the required to convert 1 mol H2O(l) at 100°C into 1 mol H2O(g) at 100°C.
q(4) = 1.00 mol ×40.7×103 J/mol = 4.07 ×104 J
The given enthalpy of vaporization is multiplied by the mole of water to give required to convert 1 mol H2O(l) at 100°C into 1 mol H2O(g) at 100°C.
To calculate the required to heat H2O(g) from 100°C to 140°C.
q(5) = 2.30J°C.g×18.2g×(140−100)°C = 1.5 ×103 J
- The given values are plugging in equation (1) to give required to heat H2O(g) from 100°C to 140°C.
- Required to heat H2O(g) from 100°C to 140°C is 1.5 ×103 J.
To calculate the amount of heat required to convert 1.00 mol of H2O(s) at -30°C to H2O(g) at 140°C.
qtotal= q1+q2+q3+q4+q5qtotal= 1.1 ×103 J+6.02×103 J+ 7.53 ×103 J+4.07 ×104 J+1.5 ×103 J = 5.69 ×104 J = 56.9 kJ
Conclusion
The heat required to convert 1.00 mol of H2O(s) at -30°C to H2O(g) at 140°C was calculated by using given specific heat capacities of water and temperatures and enthalpies and the amount of heat required to convert 1.00 mol of H2O(s) at -30°C to H2O(g) at 140°C was found to be 56.9 kJ.
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Chapter 6 Solutions
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