Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 5.4, Problem 9P
Assign relative priorities to each set of substituents:
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What is true about the relationship between the following compounds?
CH3
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O All three are stereoisomers of each other.
OA and B are the same compound while C is a stereoisomer.
All three are the same compound.
A and B are the same while C is a conformer, all of the same compound .
O A and C are the same while B is a stereoisomer.
Assign priorities to these set of Substituents
Indicate whether the pair of structures shown represent stereoisomers, constitutional isomers,
different conformations of the same compound, or the same conformation of a compound viewed from
a different perspective.
Note that cis, trans isomers are an example of stereoisomers.
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given option
stereoisomers
constitutional isomers
different conformations
same conformation
Chapter 5 Solutions
Organic Chemistry
Ch. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 4PCh. 5.2 - Prob. 5PCh. 5.2 - Draw the structure for each of the following: a....Ch. 5.2 - What is each compounds systematic name?Ch. 5.4 - Assign relative priorities to each set of...Ch. 5.4 - Tamoxifen slows the growth of some breast tumors...Ch. 5.4 - Draw and label the E and Z isomers for each of the...Ch. 5.4 - Prob. 12PCh. 5.4 - Name each of the following:
Ch. 5.4 - Prob. 14PCh. 5.4 - Prob. 15PCh. 5.6 - Prob. 16PCh. 5.6 - Prob. 17PCh. 5.6 - Prob. 18PCh. 5.6 - Prob. 20PCh. 5.7 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.7 - a. for which reaction in each set will S be more...Ch. 5.7 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.7 - Prob. 25PCh. 5.7 - Prob. 26PCh. 5.7 - Prob. 27PCh. 5.9 - The rate constant for a reaction can be increased...Ch. 5.9 - Prob. 30PCh. 5.9 - a. Which reaction has a greater equilibrium...Ch. 5.10 - Draw a reaction coordinate diagram for a two-step...Ch. 5.10 - a. Which step in the reaction coordinate diagram...Ch. 5.10 - Draw a reaction coordinate diagram for the...Ch. 5.11 - Prob. 35PCh. 5 - What is each compounds systematic name?Ch. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 39PCh. 5 - Prob. 40PCh. 5 - Name the following:Ch. 5 - Prob. 42PCh. 5 - 43. Draw the skeletal structure of...Ch. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 46PCh. 5 - Prob. 47PCh. 5 - Assign relative priorities to each set of...Ch. 5 - Prob. 49PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 51PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 53PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 56PCh. 5 - Prob. 57PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 59PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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- Give the IUPAC name for each polyfunctional compound.arrow_forwardeck the box under each compound that exists as a pair of cis/trans isomers. If none of them do, check the none of the ve box under the table. OH CI CH3 ? НО —с—CH—ОН CH3-C=C –CH3 ОН ОН CH3 CI НО C=C CH3 C=C -CH3 O none of the abovearrow_forwardQ9. Draw all the four possible stereoisomers of compound 1 using dashed/filled wedge bonds to show the relative position of substituents in space. ndicate the enantiomeric or diastereomeric relationship between each pair of isomers. OH .COOH H3C 1arrow_forward
- Assign relative priorities to each set of substituents: a. ¬Br ¬I ¬OH ¬CH3b. ¬CH2CH2OH ¬OH ¬CH2Cl ¬CH“CH2arrow_forwardput the correct substituentarrow_forwardExamples: Name the following compounds: Parent chain: Substituent(s): Position of each substituent: Name: Parent chain: Substituent(s): Position of each substituent: Name: Parent chain: Substituent(s): Position of each substituent: Name:arrow_forward
- What is relationship between the two structures shown below? CI H CH3 H-NH2 CI- -H- H NH2 ČH;CH3arrow_forwardDraw all three possible structures of benzene containing two methly (-CH3) substituents.arrow_forward10) Circle each achiral molecule among those shown below. BiH. C/ CI Br OH CH3arrow_forward
- Draw the three constitutional isomers having molecular formula C7H14 that contain a five-membered ring and two methyl groups as substituents. For each constitutional isomer that can have cis and trans isomers, draw the two stereoisomers.arrow_forwardParent chain: Substituent(s): Position of each substituent: OH Name: Parent chain: OH Substituent(s): Position of each substituent: Name: Parent chain: он Substituent(s): Position of each substituent: Name: Parent chain: Но- Substituent(s): Position of each substituent: Br Name: Parent chain: Substituent(s): Position of each substituent: он Name:arrow_forwardQ2 / Draw the following compounds so that they are optically active. A ) Br-CH2-CH2 -CH(CI)-CH(CI)-CH2-CH2-Br B) OH-CH2-CH(CH3)-CH2-CH(CH3)-CH2-OH B/ Draw the following compound in a chair position. RAarrow_forward
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