Concept explainers
Interpretation:
Movement of electrons should be indicated using curved arrows for the given reaction.
Concept introduction:
Curved arrows show the bonds that are formed and the bonds that are broken in a reaction.
Curved arrows used to understand a reaction mechanism.
Curved arrows are drawn to show how the electrons move as new covalent bonds are formed existing covalent bonds are broken.
Each arrow represents the simultaneous movement of two electrons from a nucleophile towards an electrophile.
The tail of the arrow is positioned where the electrons are in the reactant; the tail always starts at a lone pair of electron or at a bond.
The head of the arrow points to where these same electrons end up in the product; the arrow always points at an atom or a bond.
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Chapter 5 Solutions
ORGANIC CHEMISTRY W/SSM >CB<
- Aldehydes and ketones react with thiols to yield thioacetals just as they react with alcohols to yield acetals. Predict the product of the following reaction, and propose a mechanism:arrow_forwardPredict the product(s) and provide the mechanism for each reaction below.arrow_forwardDraw the products of the following reactions, including their configurations:arrow_forward
- Predict the product(s) and provide the mechanism for each reaction below. What does each mechanism have in common?arrow_forwardPropose a mechanism to account for the formation of this substitution product. Use a bromine radical as a starting product, and only draw the following as the final product:arrow_forwardPredict the products for each of the following reactions and propose a mechanism that explains the formation of each product.arrow_forward
- Provide reaction mechanisms for the following transformationsarrow_forwardPredict the products for the following reactions, showing the complete mechanism and appropriate stereochemistry:arrow_forwardPredict the product(s) and propose a mechanism for the following reaction. OH 8 Exo Hanarrow_forward
- EBK A SMALL SCALE APPROACH TO ORGANIC LChemistryISBN:9781305446021Author:LampmanPublisher:CENGAGE LEARNING - CONSIGNMENT
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