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(a)
To determine: The fisher projection for the given perspective formula.
Interpretation: The given perspective formula is to be converted into fisher projection.
Concept introduction: An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached to asymmetric carbon atoms are arranged according to their configuration in Fisher projection.
(b)
To determine: The fisher projection for the given perspective formula.
Interpretation: The given perspective formula is to be converted into fisher projection
Concept introduction: An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached to asymmetric carbon atoms are arranged according to their configuration in Fisher projection.
(c)
To determine: The fisher projection for the given perspective formula.
Interpretation: The given perspective formula is to be converted into fisher projection
Concept introduction: An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached to asymmetric carbon atoms are arranged according to their configuration in Fisher projection.
(d)
To determine: The fisher projection for the given perspective formula.
Interpretation: The given perspective formula is to be converted into fisher projection
Concept introduction: An asymmetric carbon atom is represented as a cross in Fisher projection. The carbon chain is kept along the vertical line. The groups attached to asymmetric carbon atoms are arranged according to their configuration in Fisher projection.
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Chapter 5 Solutions
ORGANIC CHEMISTRY
- What is the configuration of the two chiral centers in the following molecule?arrow_forward1) Below you are given the structures of the disaccharides lactose and trehalose. он он но он но но OH но но OH но он но но OH Lactose Trehalose a. Identify clearly the hemiacetal and acetal groups in these disaccharides and determine for each of these identified groups if they have a- or B-configuration.arrow_forwardDraw the perspective form of the newman projection from the viewpoint indicated below by the arrowarrow_forward
- In Fischer projections, the horizontal bonds represent groups projecting forward (on wedges) and the vertical bonds represent groups projecting backwards (on dashes). True or False True Falsearrow_forwardwhat is the absolute configuration on each of the chiral centers.arrow_forwardDetermine the # of chiral centers. Determine the most stable chair conformation then indicate which are equatorial and which are axial.arrow_forward
- Specify the absolute configuration in the chiral carbons in the following moleculearrow_forwardTasks Demonstrate the usefulness of Fischer projections by showing how it is easy to determine isomeric relationship between two structures. 1. Convert both isomers in Figure 8 to Fischer projections. 2. Identify the stereoisomeric relationship between the isomers. Briefly explain the process. ОН CI Br „Br "CI HO, isomer A isomer B Figure 8: Isomersarrow_forwardDraw the Fischer projection from the chair conformation shown below. OH OH H H HO -OH H OH H H Drawing Qarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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