Chemistry In Context
9th Edition
ISBN: 9781259638145
Author: Fahlman, Bradley D., Purvis-roberts, Kathleen, Kirk, John S., Bentley, Anne K., Daubenmire, Patrick L., ELLIS, Jamie P., Mury, Michael T., American Chemical Society
Publisher: Mcgraw-hill Education,
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Chapter 5, Problem 42Q
Write a response to this statement: “Because of the First Law of
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Chapter 5 Solutions
Chemistry In Context
Ch. 5.1 - Prob. 5.1YTCh. 5.1 - Prob. 5.2YTCh. 5.1 - Consult the interactive trends found in the...Ch. 5.1 - Prob. 5.4YTCh. 5.2 - For each of the fuels below, write the balanced...Ch. 5.2 - Prob. 5.6YTCh. 5.3 - Prob. 5.7YTCh. 5.4 - Prob. 5.8YTCh. 5.4 - Prob. 5.9YTCh. 5.4 - Scientific Practices Coal Versus Ethanol On the...
Ch. 5.5 - Prob. 5.12YTCh. 5.5 - Prob. 5.13YTCh. 5.6 - Although power plants require several steps to...Ch. 5.7 - Prob. 5.15YTCh. 5.7 - Prob. 5.16YTCh. 5.7 - An input of energy can be used to decrease entropy...Ch. 5.8 - Prob. 5.18YTCh. 5.8 - Prob. 5.19YTCh. 5.8 - Prob. 5.20YTCh. 5.8 - Prob. 5.21YTCh. 5.10 - Prob. 5.22YTCh. 5.11 - The combustion of one gram of natural gas releases...Ch. 5.11 - a. During the extraction of natural gas, the...Ch. 5.12 - Prob. 5.25YTCh. 5.13 - Prob. 5.26YTCh. 5.13 - Beginning in the 1920s, the octane-booster...Ch. 5.15 - Prob. 5.28YTCh. 5.15 - Prob. 5.29YTCh. 5.16 - Prob. 5.30YTCh. 5.17 - Have you ever been served cherries Jubilee or...Ch. 5.17 - Prob. 5.34YTCh. 5 - Prob. 1QCh. 5 - Prob. 2QCh. 5 - Prob. 3QCh. 5 - Energy exists in different forms in our natural...Ch. 5 - A coal-burning power plant generates electrical...Ch. 5 - Prob. 6QCh. 5 - Prob. 7QCh. 5 - Prob. 8QCh. 5 - Mercury (Hg) is present in trace amounts in coal,...Ch. 5 - Prob. 10QCh. 5 - Here are the condensed structural formulas for two...Ch. 5 - Prob. 12QCh. 5 - Prob. 13QCh. 5 - Consider these three hydrocarbons: At room...Ch. 5 - During petroleum distillation, kerosene and...Ch. 5 - Prob. 16QCh. 5 - a. Write the balanced chemical equation for the...Ch. 5 - Prob. 18QCh. 5 - Prob. 19QCh. 5 - State whether these processes are endothermic or...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Use the bond energies in Table 5.1 to calculate...Ch. 5 - Ethanol can be produced by fermentation. Another...Ch. 5 - Here are structural formulas for ethane, ethene...Ch. 5 - These three compounds all have the same chemical...Ch. 5 - Catalysts speed up cracking reactions in oil...Ch. 5 - Explain why cracking is a necessary part of the...Ch. 5 - Consider this equation representing the process of...Ch. 5 - Prob. 29QCh. 5 - Consider these three alcohols: methanol, ethanol,...Ch. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Compare and contrast a molecule of biodiesel with...Ch. 5 - Use Figure 5.6 to compare the energy released for...Ch. 5 - Prob. 36QCh. 5 - The sustainability of burning coal (and other...Ch. 5 - In this chapter, we approximated the chemical...Ch. 5 - Prob. 39QCh. 5 - Compare the processes of combustion and...Ch. 5 - How might you explain the difference between...Ch. 5 - Write a response to this statement: Because of the...Ch. 5 - The concept of entropy and probability is used in...Ch. 5 - Bond energies such as those in Table 5.1 are...Ch. 5 - Use the bond energies in Table 5.1 to explain why...Ch. 5 - Prob. 46QCh. 5 - Prob. 47QCh. 5 - Prob. 48QCh. 5 - Prob. 49QCh. 5 - Prob. 50QCh. 5 - Prob. 51QCh. 5 - Prob. 52QCh. 5 - Prob. 53QCh. 5 - Use a diagram to show the relationship among these...Ch. 5 - On a timescale of a few years, the combustion of...Ch. 5 - Emissions of some pollutants are lower when...Ch. 5 - Although coal contains only trace amounts of...Ch. 5 - Prob. 58QCh. 5 - An article in Scientific American pointed out that...Ch. 5 - C. P. Snow, a noted scientist and author, wrote an...Ch. 5 - Chemical explosions are very exothermic reactions....Ch. 5 - Prob. 63QCh. 5 - Tetraethyllead (TEL) was first approved for use in...Ch. 5 - Tetraethyllead (TEL) has an octane rating of 270....Ch. 5 - Another type of catalyst used in the combustion of...Ch. 5 - Figure 5.8 shows energy differences for the...Ch. 5 - Prob. 68Q
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- The statement Energycan beneithercreatednor destroyedis sometimes used as an equivalent statement of the first law of thermodynamics. There areinaccuracies to the statement, however. Restate it tomake it less inaccurate.arrow_forwardThe second law of thermodynamics is sometimes paraphrased as: you can't break even. Explain. Because energy cannot be created out of nothing. Because some energy is lost in all energy transactions. Because some energy is gained in all energy transactons.arrow_forwardExplain why absolute enthalpies and energies cannot be measured, and only changes can be determined.arrow_forward
- A pot of cold water is heated on a stove, and when the water boils, a fresh egg is placed in the water to cook. Describe the events that are occurring in terms of the zeroth law of thermodynamics.arrow_forward9.72 Although it can be a nuisance when a laptop computer freezes up and needs to be rebooted, we accept that as somewhat inevitable. But clearly the need to occasionally reboot the control system for the power grid would not be acceptable. Use the web to research ways that engineers ensure the reliability of crucial systems like the control infrastructure of the grid, and write a paragraph summarizing the main strategies employed.arrow_forwardCoal is used as a fuel in some electric-generating plants. Coal is a complex material, but for simplicity we may consider it to be a form of carbon. The energy that can be derived from a fuel is sometimes compared with the enthalpy of the combustion reaction: C(s)+O2(g)CO2(g) Calculate the standard enthalpy change for this reaction at 25C. Actually, only a fraction of the heat from this reaction is available to produce electric energy. In electric generating plants, this reaction is used to generate heat for a steam engine, which turns the generator. Basically the steam engine is a type of heat engine in which steam enters the engine at high temperature (Th), work is done, and the steam then exits at a lower temperature (Tl). The maximum fraction, f, of heat available to produce useful energy depends on the difference between these temperatures (expressed in kelvins), f = (Th Tl)/Th. What is the maximum heat energy available for useful work from the combustion of 1.00 mol of C(s) to CO2(g)? (Assume the value of H calculated at 25C for the heat obtained in the generator.) It is possible to consider more efficient ways to obtain useful energy from a fuel. For example, methane can be burned in a fuel cell to generate electricity directly. The maximum useful energy obtained in these cases is the maximum work, which equals the free-energy change. Calculate the standard free-energy change for the combustion of 1.00 mol of C(s) to CO2(g). Compare this value with the maximum obtained with the heat engine described here.arrow_forward
- The decomposition of ozone, O3, to oxygen, O2, is an exothermic reaction. What is the sign of q? If you were to touch a flask in which ozone is decomposing to oxygen, would you expect the flask to feel warm or cool?arrow_forward9.42 Why is enthalpy generally more useful than internal energy in the thermodynamics of real world systems?arrow_forwardIn a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each experiment. Since the amount of water is not constant from experiment to experiment, the mass of water must be measured in each case. The heat capacity of the calorimeter is broken down into two parts: the water and the calorimeter components. If a calorimeter contains 1.00 kg water and has a total heat capacity of 10.84 kJ/C, what is the heat capacity of the calorimeter components?arrow_forward
- Which of the following processes is endothermic? a. ice melting b. a piece of paper burning c. a bomb exploding d. an organisms metabolism producing a certain amount of heatarrow_forwardThe enthalpy change for the following reaction is 393.5 kJ. C(s,graphite)+O2(g)CO2(g) (a) Is energy released from or absorbed by the system in this reaction? (b) What quantities of reactants and products are assumed? (c) Predict the enthalpy change observed when 3.00 g carbon burns in an excess of oxygen.arrow_forwardGasohol, a mixture of gasoline and ethanol, C2H5OH, is used as automobile fuel. The alcohol releases energy in a combustion reaction with O2. C2H5OH(l)+3O2(g)2CO2(g)+3H2O(l) If 0.115 g ethanol evolves 3.62 kJ when burned at constant pressure, calculate the combustion enthalpy for ethanol.arrow_forward
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