FUNDAMENTALS OF PHYSICS (LLF)+WILEYPLUS
FUNDAMENTALS OF PHYSICS (LLF)+WILEYPLUS
11th Edition
ISBN: 9781119459132
Author: Halliday
Publisher: WILEY
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Chapter 44, Problem 42P

Due to the presence everywhere of the cosmic background radiation, the minimum possible temperature of a gas in interstellar of intergalactic space is not 0 K but 2.7 K. This implies that a significant fraction of the molecules in space that can be in a low-level excited state may, in fact, be so. Subsequent de-excitation would lead to the emission of radiation that could be detected. Consider a (hypothetical) molecule with just one possible excited state. (a) What would the excitation energy have to be for 25% of the molecules to be in the excited state? (Hint: See Eq. 40-29.) (b) What would be the wavelength of the photon emitted in a transition back to the ground state?

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Due to the presence everywhere of the cosmic background radiation, the minimum possible temperature of a gas in interstellar or intergalactic space is not 0 K but 2.7 K. This implies that a significant fraction of the molecules in space that can be in a lowlevel excited state may, in fact, be so. Subsequent de-excitation would lead to the emission of radiation that could be detected. Consider a (hypothetical) molecule with just one possible excited state. (a) What would the excitation energy have to be for 25% of the molecules to be in the excited state? (b) What would be the wavelength of the photon emitted in a transition back to the ground state?
The partition function of an ensemble at a temperature T is N Z = (2 cosh kgT where kg is the Boltzmann constant. The heat capacity of this ensemble at T = is X Nkg, where the value of X is %3D kB (up to two decimal places).
1 (a) Show that the entropy per photon in blackbody radiation is independent of the temperature, and in d spatial dimensions is given by En-d-1 s = (d + 1) n=1 E n-d n=1 (b) Show that the answer would have been d + 1 if the photons obeyed Boltzman statistics.
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