Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 4.12, Problem 29ATS

(a)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformations of given compounds are drown and the given Bromine atome is in equatorial position of given Newman projection has to be identified.

Concept Introduction:

Conformational isomers:

  • The two or more compounds have same molecular formula and different structural formulas are called conformational isomers.
  • The Cyclohexane s have a chair and boat conformations.
  • The chair conformation of Cyclohexane is more stable than boat form.
  • The chair conformation of Cyclohexane have two positions to substituents which are axial and equatorial.
  • The substituent occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.
  • The substituent occupy at similar to a horizontal axis passing through the chair conformation of Cyclohexane ring is called equatorial position.

(b)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformations of given compounds are drown and the given Bromine atome is in equatorial position of given Newman projection has to be identified.

Concept Introduction:

Conformational isomers:

  • The two or more compounds have same molecular formula and different structural formulas are called conformational isomers.
  • The Cyclohexane s have a chair and boat conformations.
  • The chair conformation of Cyclohexane is more stable than boat form.
  • The chair conformation of Cyclohexane have two positions to substituents which are axial and equatorial.
  • The substituent occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.
  • The substituent occupy at similar to a horizontal axis passing through the chair conformation of Cyclohexane ring is called equatorial position.

(c)

Interpretation Introduction

Interpretation:

The axial and equatorial chair conformations of given compounds are drown and the given Bromine atome is in equatorial position of given Newman projection has to be identified.

Concept Introduction:

Conformational isomers:

  • The two or more compounds have same molecular formula and different structural formulas are called conformational isomers.
  • The Cyclohexane s have a chair and boat conformations.
  • The chair conformation of Cyclohexane is more stable than boat form.
  • The chair conformation of Cyclohexane have two positions to substituents which are axial and equatorial.
  • The substituent occupy at similar to a vertical axis passing through the chair conformation of Cyclohexane ring is called axial position.
  • The substituent occupy at similar to a horizontal axis passing through the chair conformation of Cyclohexane ring is called equatorial position.

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Chapter 4 Solutions

Organic Chemistry

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