Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 4.1, Problem 5P
Interpretation Introduction
Interpretation:
The three compounds with a double bond showing no cis-trans isomer for the given molecular formula has to be drawn.
Concept introduction:
Cis-trans terminology is used for two non-similar groups attached
If the two identical groups are attached on each side of double bond in same side, then it is cis alkenes.
If the two identical groups are attached on each side of double bond in opposite manner, then it is trans alkenes.
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Chapter 4 Solutions
Organic Chemistry
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- Draw the structure of a hydrocarbon with molecular formula C6H10 that also contains: (a) a carbon–carbon triple bond; (b) two carbon–carbon double bonds; (c) one ring and one C=C.arrow_forwardA saturated straight-chain alcohol has a molecular formula of C₆H₁₃OH. Draw the corresponding skeletal structure. C-H bonds are implied.arrow_forwardDraw skeletal structures for the cyclopropane (three- membered ring) isomers with a formula of C5H10. Note: cyclopropane is a carbon-carbon ring with three carbons.arrow_forward
- Two compounds with the formula CH3 ¬ CH “ N ¬ CH3 are known Explain why only one compound with the formula (CH3)2CNCH3 is knownarrow_forwardDraw and name the four cycloalkanes of formula C6H12 that do have cis-trans isomers.arrow_forwardDraw skeletal structures for the cyclopropane (three-membered ring) isomers with a formula of C₅H₁₀. Note: cyclopropane is a carbon-carbon ring with three carbons. Three isomersarrow_forward
- Draw a skeletal ("line") structure of this molecule: CH3 CH3C−CH2−O−CH2OH CH3arrow_forwardCyclopropane (C3H6, a three-membered ring) is more reactive than most other cycloalkanes.(a) Draw a Lewis structure for cyclopropane.(b) Compare the bond angles of the carbon atoms in cyclopropane with those in an acyclic (noncyclic) alkane.(c) Suggest why cyclopropane is so reactive.arrow_forwardDraw all the possible structural isomers with the molecular formula C6H14, Name themarrow_forward
- What are the names of two constitutional isomers of the chemical formula C6H14? Do not choose hexane as one of the structures. 2-methylpentane 2,3-dimethylpentane 3-methylpentane 3-ethylpentane 2-methylhexanearrow_forwardWhich of the following is NOT a skeletal isomer of C6H14?arrow_forwardIn 1874, Dutch chemist Jacobus van't Hoff (1852–1911) and French chemist Joseph Le Bel (1847–1930) independently deduced that a carbon atom bonded to four atoms assumes a tetrahedral geometry. Prior to that time, it was believed that tetravalent carbons assumed a square planar geometry. One piece of evidence that can be used to support a tetrahedral geometry is the fact that molecules with the general formula CX2Y2 (where X and Y are either a hydrogen or a halogen atom) are always polar. Explain how this supports a tetrahedral geometry and rules out a square planar geometry. Square planar geometry Tetrahedral geometryarrow_forward
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