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EBK INORGANIC CHEMISTRY
5th Edition
ISBN: 9780133558944
Author: Tarr
Publisher: PEARSON CUSTOM PUB.(CONSIGNMENT)
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Textbook Question
Chapter 4, Problem 4.7P
Determine the point groups for
a. A sheet of typing paper
b. An Erlenmeyer flask (no label)
c. A screw
d. The number 96
e. Five examples of objects from everyday life; select items from five different point groups
f. A pair of eyeglasses, assuming lenses of equal strength
g. A five-pointed star
h. A fork with no decoration
i. Wilkins Micawber, David Copperfield character who wore a monocle
j. A metal washer
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Students have asked these similar questions
In which point group are the letters A, F, N respectively?
What is the point group of NOCl?
a. C∞v
b. Cs
c. none of the above is a correct point group
d. D∞h
e. C2v
f. D2h
7.
The following character table (accompanied by a molecule of the corresponding point
group) has some missing information.
E
2 C3
3 C2
?
2 S3
3 oy
X1
1
1
1
1
1
x2+ y?, z2
A2
1
1
-1
1
-1
Rz
E'
2
-1
2
-1
(х, у)
(x2- у?, ху)
A,"
1
X2
1
-1
-1
-1
A2"
1
1
-1
-1
-1
1
X3
BH3
E"
2
-1
-2
1
(Rx, Ry)
(zx, yz)
а.
Based on symmetry labels and Mulliken symbols, what is the missing symmetry element?
b. Provide the missing information in the table:
i. X1 =
ii. X2 =
iii. X3 =
С.
For this point group, what is the symmetry of the following orbitals for an atom located along
the main C3 axis?
i. А Рх
orbital:
ii. A d,? orbital:
iii. A dxy orbital:
Chapter 4 Solutions
EBK INORGANIC CHEMISTRY
Ch. 4.1 - Prob. 4.1ECh. 4.1 - Find all the symmetry elements in the following...Ch. 4.2 - Use the procedure described previously to verify...Ch. 4.3 - Prob. 4.4ECh. 4.3 - Verify the transformation matrices for the E and...Ch. 4.3 - Prepare a representation flowchart according to...Ch. 4.4 - Which point groups are possible for chiral...Ch. 4.4 - Write the corresponding 99 transformation matrices...Ch. 4.4 - Using the x, y, and z coordinates for each atom in...Ch. 4.4 - Reduce the following representations to their...
Ch. 4.4 - Prob. 4.11ECh. 4.4 - Analysis of the x, y, and z coordinates of each...Ch. 4.4 - Determine the number of IR-active CO stretching...Ch. 4.4 - Prob. 4.14ECh. 4 - Determine the point groups for a. Ethane...Ch. 4 - Determine the point groups for a. Ethylene b....Ch. 4 - Determine the point groups for a. Acetylene b....Ch. 4 - Determine the point groups for a. Naphthalene b....Ch. 4 - Determine the point groups for a. 1,1’ ...Ch. 4 - Determine the point groups for a. Cyclohexane...Ch. 4 - Determine the point groups for a. A sheet of...Ch. 4 - Determine the point groups for a. A flat oval...Ch. 4 - Determine the point groups for a. A triangular...Ch. 4 - Determine the point groups for the examples of...Ch. 4 - Determine the point groups of the molecules in the...Ch. 4 - Determine the point groups of the molecules and...Ch. 4 - Determine the point groups of the following atomic...Ch. 4 - a. Show that a cube has the same symmetry elements...Ch. 4 - Suppose an octahedron can have either yellow or...Ch. 4 - What point groups are represented by the symbols...Ch. 4 - Prob. 4.17PCh. 4 - Determine the point groups for the following flags...Ch. 4 - Prepare a representation flowchart according to...Ch. 4 - For trans-1,2-dichloroethylene, which has C2h...Ch. 4 - Ethylene has D2h symmetry. a. List all the...Ch. 4 - Using the D2d character table, a. Determine the...Ch. 4 - Reduce the following representations to...Ch. 4 - For D4h symmetry use sketches to show that dxy...Ch. 4 - Prob. 4.25PCh. 4 - XeOF4 has one of the more interesting structures...Ch. 4 - Repeat the procedure from the previous problem,...Ch. 4 - For the following molecules, determine the number...Ch. 4 - Prob. 4.29PCh. 4 - The structure of 1,1,2,2-tetraiododisilane is...Ch. 4 - Both cis and trans isomers of IO2F4 have been...Ch. 4 - White elemental phosphorus consists of tetrahedral...Ch. 4 - Complexes of the general formula Fe(CO)5x( PR3)x...Ch. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Determine the point groups of the following...Ch. 4 - Prob. 4.40PCh. 4 - Determine the point groups of the following: a....Ch. 4 - Use the Internet to search for molecules with the...
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