General Chemistry
General Chemistry
4th Edition
ISBN: 9781891389603
Author: Donald A. McQuarrie, Peter A. Rock, Ethan B. Gallogly
Publisher: University Science Books
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Chapter 4, Problem 4.61P
Interpretation Introduction

Interpretation:

The color of visible light that has enough energy to eject an electron from metal foil that has threshold frequency of 5.45×1014Hz has to be identified.

Concept Introduction:

The minimum frequency of radiation that is required to eject an electron from metal is known as threshold frequency (ν0) of the metal.  This value differs for each and every metal.  Minimum energy that is required to eject an electron is hν0.

Energy that is required in excess to eject an electron is given by the equation shown below.

    E=hνhν0

Expert Solution & Answer
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Explanation of Solution

Threshold frequency for metal is given as 5.45×1014Hz.  This is same as 5.45×1014s-1.  The minimum energy that is required to eject an electron the given metal foil is calculated as shown below.

    E=hν0=6.626×1034Js×5.45×1014s-1=36.1117×1020J=36.11×1020J=3.611×10-19J

Violet light is said to have wavelength of 400nm.  Therefore, the energy of photon that has wavelength of 400nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1400×109m=0.0496602135×1017J=4.96×1019J

Indigo light is said to have wavelength of 445nm.  Therefore, the energy of photon that has wavelength of 445nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1445×109m=0.04463839416×1017J=4.45×1019J

Blue light is said to have wavelength of 475nm.  Therefore, the energy of photon that has wavelength of 475nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1475×109m=0.04181912715×1017J=4.18×1019J

Green light is said to have wavelength of 510nm.  Therefore, the energy of photon that has wavelength of 510nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1510×109m=0.0389491870×1017J=3.89×1019J

Yellow light is said to have wavelength of 570nm.  Therefore, the energy of photon that has wavelength of 570nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1570×109m=0.034849272×1017J=3.48×1019J

Orange light is said to have wavelength of 590nm.  Therefore, the energy of photon that has wavelength of 590nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1590×109m=0.0336679413×1017J=3.37×1019J

Red light is said to have wavelength of 650nm.  Therefore, the energy of photon that has wavelength of 650nm is calculated as shown below.

    E=hcλ=6.626×1034Js×2.9979×108ms1650×109m=0.0305601313×1017J=3.06×1019J

In order to eject an electron from the metal foil, the energy of photon has to be at least 3.611×10-19J.  Therefore, electrons will be ejected by Green, Blue, Indigo, and Violet light.

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