(a) Interpretation: Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer. Concept introduction: In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

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Answer 1

Question

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

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Draw the structure and give the molecular formula of each of the following compounds:d) 3-ethyl-1,1-diiso-propylcyclohexanee) 3-isopropyl-2,4-dimethylhexanef) 1,1-diethyl-4-(3,3-dimethylbutyl)cyclohexane

How To Draw the Two Conformations for a Substituted Cyclohexane ?

Exclusive of compounds with double bonds, four hydrocarbons are constitutional isomers of cis- and trans-1,2-dimethylcyclopropane. Identify these compounds.

Answer 2

Question

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

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Answer 3

Question

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

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Answer 4

Question

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

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Answer 5

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 6

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 7

Chapter 4, Problem 4.43P

Interpretation Introduction

(a)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 10

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 11

Interpretation Introduction

(c)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 12

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 13

Interpretation Introduction

(d)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 14

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 15

Interpretation Introduction

(e)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 16

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 17

Interpretation Introduction

(f)

Interpretation:

Each of the given disubstituted cyclohexane is to be identified as either a cis or trans isomer.

Concept introduction:

In case of disubstituted cyclohexane, the substituents which are on the opposite side of the ring are trans to each other. Substituents are said to be cis, if they lie on the same side of the ring. Substituents that are trans to each other in one chair conformation remains trans after the chair flip and substituents which are cis to each other remain cis.

Answer 18

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Answer 19

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Answer 20

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Answer 21

Ch. 4 - Prob. 4.1P Ch. 4 - Prob. 4.2P Ch. 4 - Prob. 4.3P Ch. 4 - Prob. 4.4P Ch. 4 - Prob. 4.5P Ch. 4 - Prob. 4.6P Ch. 4 - Prob. 4.7P Ch. 4 - Prob. 4.8P Ch. 4 - Prob. 4.9P Ch. 4 - Prob. 4.10P

Solution Summary: The author explains that each of the disubstituted cyclohexane is to be identified as either a cis or trans isomer.

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Chapter 4 Solutions