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Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Question
Chapter 4, Problem 4.30P
Interpretation Introduction
Interpretation:
The free-energy diagram for a reaction
Concept introduction:
The transition state is formed during the conversion of reactants into products in the
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Students have asked these similar questions
Given the following reaction:
HNO2(aq) + H2O(l) ⇄ NO2–(aq) + H3O+(aq)
What happens when some HNO2(aq) is removed from the solution?
Group of answer choices
A. The rate of the reverse reaction increases, producing more H3O+(aq).
b. The rate of the forward reaction increases, producing more H3O+(aq).
C. The rate of the reverse reaction increases, producing more HNO2(aq).
D. The rate of the forward reaction increases, producing more HNO2(aq).
When the reaction A+BC is at equilibrium, the concentration of the reactants are as follows; [A] = 2mM, [B] = 3mM, and [C] = 9mM. What is the standard free energy change for the reaction?
DG° < 0, DH° < 0 and DS° < 0 is it this if the reaction is H2O (l) →→ H2O (s) occurring at -20°C and standard conditions..
Chapter 4 Solutions
Organic Chemistry Study Guide and Solutions
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Prob. 4.8PCh. 4 - Prob. 4.9PCh. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11PCh. 4 - Prob. 4.12PCh. 4 - Prob. 4.13PCh. 4 - Prob. 4.14PCh. 4 - Prob. 4.15PCh. 4 - Prob. 4.16PCh. 4 - Prob. 4.17PCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21PCh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23PCh. 4 - Prob. 4.24PCh. 4 - Prob. 4.25PCh. 4 - Prob. 4.26PCh. 4 - Prob. 4.27PCh. 4 - Prob. 4.28PCh. 4 - Prob. 4.29PCh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31PCh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Prob. 4.39PCh. 4 - Prob. 4.40APCh. 4 - Prob. 4.41APCh. 4 - Prob. 4.42APCh. 4 - Prob. 4.43APCh. 4 - Prob. 4.44APCh. 4 - Prob. 4.45APCh. 4 - Prob. 4.46APCh. 4 - Prob. 4.47APCh. 4 - Prob. 4.48APCh. 4 - Prob. 4.49APCh. 4 - Prob. 4.50APCh. 4 - Prob. 4.51APCh. 4 - Prob. 4.52APCh. 4 - Prob. 4.53APCh. 4 - Prob. 4.54APCh. 4 - Prob. 4.55APCh. 4 - Prob. 4.56APCh. 4 - Prob. 4.57APCh. 4 - Prob. 4.58APCh. 4 - Prob. 4.59APCh. 4 - Prob. 4.60APCh. 4 - Prob. 4.61APCh. 4 - Prob. 4.62APCh. 4 - Prob. 4.63APCh. 4 - Prob. 4.64APCh. 4 - Prob. 4.65APCh. 4 - Prob. 4.66APCh. 4 - Prob. 4.67APCh. 4 - Prob. 4.68APCh. 4 - Prob. 4.69APCh. 4 - Prob. 4.70AP
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- Organic Chemistry Loudon | Parise SEVENTH EDITION A reaction A(aq) + B(aq) = C(aq) has a standard free-energy change of −3.87 kJ/mol at 25 °C. What are the concentrations of A, B, and C at equilibrium if, at the beginning of the reaction, their concentrations are 0.30 M, 0.40 M, and 0 M, respectively? [A] = [B] = || presented by Macmillan Learning [C] = = M Enter numeric value M Marrow_forwardFor which of these reactions will the difference between AH° and AE° be the smallest? X 5 H₂(g) + Cl₂(g) → 2HCl(g) C4PH3(g) → P4(9) + 6H₂(9) ⒸP4(s) + 10Cl₂(g) → 4PC15(s) CO₂(g) + 2H₂O(1) CH4(9) + 20₂(9) ON₂(g) + 3H₂(g) → 2NH3(9) -arrow_forwardCalculate the nonstandard free energy change, ΔG, for the following reaction when P I2 = 2.50 atm, P Cl2 = 3.25 atm and P ICl = 0.210 atm. I2(g)+Cl2(g)⇌ICl(g) ΔG∘=−10.9 kJ/molarrow_forward
- predict whether a reaction with a negative deltaH and a negative deltaS will be spontaneous, nonspontaneous, or temperature dependent. explain your answer.arrow_forward24) Consider the following free energy curve for the reaction: A=B Pure A Pure B extent of reaction a) At equilibrium (2), is the system more enriched in A or in B? Provide a brief explanation of your choice. b) What would be the relative value of K? Greater than one, zero, or less than 1? Again, provide a brief explanation of your choice. free energyarrow_forwardO(g) +e- O-(g) ∆Ho= -142 kJmol-1 O+2e- O2-(g) ∆Ho= + 712 kJ mol-1Calculate ∆Hofor the reaction : O- + e- O2-(g) .arrow_forward
- 44. If the reaction A + B = C has an equilibrium constant greater than 1, which of the following statements is correct concerning the forward reaction? A) The forward reaction is not thermodynamically favored and would be considered non-spontaneous. %3D B) The forward reaction rate is fast. C) The forward reaction is slow. D) The forward reaction is thermodynamically favored and would be considered spontaneous.arrow_forwardThe standard free energy variation, at 25 ºC, for equilibrium: Glucose-6-phosphate (G-6-P) Glucose-1-phosphate (G-1-P) is ΔGº '= + 7280 J / mol. Calculate a) The equilibrium constant of the reaction. b) The real change in free energy when one mole of G-6-P is transformed into G-1-P, both concentrations remaining constant and equal to 10mM and 2 mM respectively.arrow_forwardOpen Grammarly fills a reaction vessel with 6.73 atm methane (CH4) gas, 2.27 atm oxygen (O₂) gas, 5.83 atm carbon dioxide (CO₂) gas, and 8.00 atm hydrogen (H₂) gas at a temperature of 25.0°C. Under these conditions, calculate the reaction free energy AG for the following chemical reaction: CH₂(g) + O₂(g) → CO₂(g) + 2H₂(g) 2 Use the thermodynamic information in the ALEKS Data tab. Round your answer to the nearest kilojoule. kJ X Ś ? l Ararrow_forward
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