EBK GET READY FOR ORGANIC CHEMISTRY
2nd Edition
ISBN: 9780321830555
Author: KARTY
Publisher: VST
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Question
Chapter 4, Problem 4.13P
Interpretation Introduction
Interpretation:
The most stable conformation of the molecule shown is to be drawn.
Concept introduction:
When the bulkier substituent attached to a cyclohexane ring is in the equatorial position, the chair conformation is more favored. In the disubstituted cyclohexane, the substituents that are on the opposite side of the ring are trans to each other. If there are more than one substituent attached, then the conformation in which maximum substituents are in the equatorial position is favored and is more stable. Substituents that are trans to each other in one chair conformation remain trans after the chair flip.
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Students have asked these similar questions
Problem:
Following are the alternative chair conformations for
trans-1,4-dimethylcyclohexane.
Problem: Answer the following questions about the 2-ethyl-4-isopropyl-1-
methylcylcohexane stereoisomer shown below. Be sure to draw the correct
stereoisomer! (a) Draw the lowest potential energy chair conformation. (b) Draw the
highest potential energy chair conformation. (c) Explain how you determined the
relative potential energy of your chair conformations.
CH3
CH₂CH3
CH(CH3)2
Draw the Newman projection so that it corresponds to the molecule and conformation shown when viewed down the red bond.
Chapter 4 Solutions
EBK GET READY FOR ORGANIC CHEMISTRY
Ch. 4 - Prob. 4.1PCh. 4 - Prob. 4.2PCh. 4 - Prob. 4.3PCh. 4 - Prob. 4.4PCh. 4 - Prob. 4.5PCh. 4 - Prob. 4.6PCh. 4 - Prob. 4.7PCh. 4 - Prob. 4.8PCh. 4 - Prob. 4.9PCh. 4 - Prob. 4.10P
Ch. 4 - Prob. 4.11PCh. 4 - Prob. 4.12PCh. 4 - Prob. 4.13PCh. 4 - Prob. 4.14PCh. 4 - Prob. 4.15PCh. 4 - Prob. 4.16PCh. 4 - Prob. 4.17PCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21PCh. 4 - Prob. 4.22PCh. 4 - Prob. 4.23PCh. 4 - Prob. 4.24PCh. 4 - Prob. 4.25PCh. 4 - Prob. 4.26PCh. 4 - Prob. 4.27PCh. 4 - Prob. 4.28PCh. 4 - Prob. 4.29PCh. 4 - Prob. 4.30PCh. 4 - Prob. 4.31PCh. 4 - Prob. 4.32PCh. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Prob. 4.36PCh. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Prob. 4.39PCh. 4 - Prob. 4.40PCh. 4 - Prob. 4.41PCh. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - Prob. 4.44PCh. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - Prob. 4.51PCh. 4 - Prob. 4.52PCh. 4 - Prob. 4.53PCh. 4 - Prob. 4.54PCh. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Prob. 4.57PCh. 4 - Prob. 4.58PCh. 4 - Prob. 4.59PCh. 4 - Prob. 4.60PCh. 4 - Prob. 4.61PCh. 4 - Prob. 4.62PCh. 4 - Prob. 4.63PCh. 4 - Prob. 4.64PCh. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Prob. 4.68PCh. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Prob. 4.71PCh. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Prob. 4.1YTCh. 4 - Prob. 4.2YTCh. 4 - Prob. 4.3YTCh. 4 - Prob. 4.4YTCh. 4 - Prob. 4.5YTCh. 4 - Prob. 4.6YTCh. 4 - Prob. 4.7YTCh. 4 - Prob. 4.8YTCh. 4 - Prob. 4.9YTCh. 4 - Prob. 4.10YTCh. 4 - Prob. 4.11YTCh. 4 - Prob. 4.12YTCh. 4 - Prob. 4.13YTCh. 4 - Prob. 4.14YTCh. 4 - Prob. 4.15YTCh. 4 - Prob. 4.16YTCh. 4 - Prob. 4.17YTCh. 4 - Prob. 4.18YTCh. 4 - Prob. 4.19YTCh. 4 - Prob. 4.20YTCh. 4 - Prob. 4.21YTCh. 4 - Prob. 4.22YTCh. 4 - Prob. 4.23YTCh. 4 - Prob. 4.24YTCh. 4 - Prob. 4.25YT
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Draw the most stable conformation of the molecule shown below. The most stable conformation is the one in whicharrow_forwardWhich of the conformations shown has a lower energy?arrow_forwardDraw the Newman projection so that it corresponds to the molecule and conformation shown when viewed down the red bond in the direction of the arrow.arrow_forward
- (iii) Draw the lowest energy conformer for the following compound.arrow_forwardWhich of these is the most stable conformation?arrow_forwardProblem: Perform a conformational analysis 2-iodo-2-methylbutane, looking down the C2-C3 bond. Pay attention to the relative energies of the various conformations, but do not concern yourself with the actual energy values.arrow_forward
- Problem: Perform a conformational analysis 2-iodo-2-methylbutane, looking down the C2—C3 bond. Pay attention to the relative energies of the various conformations, but do not concern yourself with the actual energy values. Pleae draw newman projections.arrow_forwardDetermine how many Gauche interactions are in the most stable chair conformation for each of the following structures.arrow_forwardProblem How many different configurational stereoisomers exist (including the one shown) for each of the following molecules?arrow_forward
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