Thermodynamics, Statistical Thermodynamics, & Kinetics
Thermodynamics, Statistical Thermodynamics, & Kinetics
3rd Edition
ISBN: 9780321824004
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 3, Problem 3.5NP
Interpretation Introduction

Interpretation:

The final temperature needs to be determined, when 34.05 g of ice at 273 K is dropped into 185 g of liquid water at 310 K.

Concept Introduction:

Chemical reactions in general involve exchange of heat between the system (reactants and products) and the surroundings. The heat (q) absorbed or evolved in order to change the temperature (ΔT) of n moles of a substance of heat capacity c is given as: q = n ×c×ΔT ------(1)

Enthalpy of fusion (ΔHfus) or the latent heat of fusion is the amount of energy required to change the state of a substance from solid to liquid

  q = n ×ΔHfus----(2)

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In a 3.0 L vessel the following equilibrium partial pressure are measured: N2= 90 torr, H2= 317 torr, NH3=1.00 x10^3 torr N2 (g) + 3H2 (g) -> 2NH3 (g) if hydrogen is removed from the vessel until the partial pressure of nitrogen, at equilibrium, is 250 torr. Calculate the partial pressure of the other substances under the new conditions. (Use the numbers at the top to find kp, then make those equilibrium conditions initial conditions to figure out this last part. The change in nitrogen will allow you (through stoich) to find the change in ammonia. The you can use Kp to find the partial pressure of hydrogen).
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Carbon monoxide and water vapor, each at 200. Torr, were introduced into a container of volume 0.250 L. When the mixture reached equilibrium at 700 degrees Celsius, the partial pressure of CO2(g) was 88 Torr. Calculate the value of K for the equilibrium CO (g) + H2O (g)⇋ CO2(g)+H2(g).

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Thermodynamics, Statistical Thermodynamics, & Kinetics

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