Concept explainers
(a)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(b)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(c)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(d)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(e)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(f)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(g)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
(h)
Interpretation:
Mirror image of the given molecule has to be drawn and also whether the original molecule and its mirror image is the same or different has to be checked.
Concept Introduction:
Chiral center:
A tetrahedral atom that is bonded to four different groups is called as chiral center. The most commonly known tetrahedral atom is carbon.
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Chapter 3 Solutions
Organic Chemistry
- Doxorubicin, shown here, is an important chemotherapy drug used to treat avariety of cancers, including bladder cancer, breast cancer, and certain forms of leukemia. Doxorubicin works by binding to DNA in such a way that a portion of it penetrates the DNA double helix— a process called intercalation. During transcription— the process that forms RNA— portions of the DNA strands are temporarily separated for the base sequence to be read and then are reconnected. With bound doxorubicin, however, the double helix does not reform properly after the strands are separated, which disrupts replication— the process that forms an identical copy of DNA. Which portion of doxorubicin do you think intercalates into the DNA double helix, and why do you think it has little difficulty doing so?arrow_forwardNaming and Drawing Organic Molecules Comparing skeletal structures related by one fewer bond Could we cut just one bond in the "starting" molecule shown in the drawing area below to create this "target" molecule? The target molecule. If so, highlight the bond to be cut. If not, check the box under the drawing area that says Not possible. Note: it's OK if cutting the bond creates more than one molecule, as long as one of them is the target molecule. Not possible. Explanation Check MacBook Air G 1/5 Julianna 2024 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Center Accessibilityarrow_forwardAlso, highlight each bond in this structure that is cis but which could be trans in a different cis/trans isomer. If there are no such bonds, check the No bonds to highlight box under the drawing area. Note: be careful not to highlight a bond just because it's cis in this drawing! It also needs to be a bond that would create a different cis/trans isomer if it were changed to trans. This molecule has cis/trans isomers in all. G Carrow_forward
- Click on all of the atoms that make up the largest coplanar unit in the molecule below. Br H H. H. H Harrow_forwarddraw the 3d model of the molecule CH3CH2CH2C[triplebond]CCH2CH2CH3 from the view of the triple bonded C atoms. Not sure if I drew the appropriate hydrogens needed on the Carbons that have the triple bond?arrow_forwardClick on all of the atoms that make up the largest coplanar unit in the molecule below. HHarrow_forward
- Consider the molecule of chloroform. Its tetrahedral structure is shown. H | CI CCI CI Is this molecule polar? If yes, consider which side of the molecule has partial negative charge and which - partial positive. Then, indicate the direction of the dipole moment relative to the molecule as shown. Non-polar, zero dipole moment. Polar. The dipole vector points along one of the C-Cl bonds. Polar. The dipole vector points along the vertical axis. parallel to the C-H bond. Polar. The dipole vector points along the horizontal axis. Polar. The dipole vector is perpendicular to the plane of the figure.arrow_forwardCould we cut just one bond in the "starting" molecule shown in the drawing area below to create this "target" molecule? The target molecule. If so, highlight the bond to be cut. If not, check the box under the drawing area that says Not possible. Note: it's OK if cutting the bond creates more than one molecule, as long as one of them is the target molecule. Not possible. X H H-C-H H-O-H H 3 Note for advanced students: what we mean by "cutting" the bond here is breaking the bond and attaching H atoms to each dangling end, like this: H H-C-0-H Harrow_forwardClick on all of the atoms that make up the largest coplanar unit in the molecule below. H H yht H Harrow_forward
- Check the box next to each molecule on the right that has the shape of the model molecule on the left: molecules model (check all that apply) O COCI, | CH;0 You can c CH4 O CH,Cl, O None of the above Note for advanced students: the length of bonds and size of atoms in the model is not necessarily realistic. Th geometry and 3D shape of the molecule.arrow_forwardSelect the bonds in the 3D representation of methyl urethane below that are multiple bonds. (Hint: Consider the number of bonds attached to an atom in the image compared to the normal valence of that atom. In a valid structure, the number of bonds to an atom will equal the valence of that atom.) • Gray = C: white = H; red = 0; blue = N; dark green = Cl; brown = Br; light green = F; purple = 1; yellow = S: orange = P. • Double click to select bonds. You can zoom in and out using the mouse scroll wheel (or pinch to zoom on touch screens). ●arrow_forwardClick on all of the atoms that make up the largest coplanar unit in the molecule below. H Н. H Harrow_forward
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning