Physical Chemistry
Physical Chemistry
3rd Edition
ISBN: 9780321812001
Author: ENGEL, Thomas/ Reid
Publisher: Pearson College Div
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Chapter 3, Problem 3.16NP
Interpretation Introduction

Interpretation: The Joule coefficient for an ideal gas and for van der Waals gas needs to be calculated.

Concept Introduction: For ideal gas, the relation between n number of moles of gas under pressure, P , volume, V at temperature, T is given as:

  PV = nRT - (1)

Where R is universal gas constant.

For van der Waals equation, the relation between n number of moles of gas under pressure, P , volume, V at temperature, T is given as:

  P = nRTV - nbn2aV2 - (2)

Where R is universal gas constant, a and b are van der Waals constant.

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