Chemistry: A Molecular Approach
3rd Edition
ISBN: 9780321809247
Author: Nivaldo J. Tro
Publisher: Prentice Hall
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Question
Chapter 3, Problem 18E
Interpretation Introduction
To explain: The combustion analysis and its use.
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4. Provide the Lewis structures for the following Lettered compounds from 'A' through
'G'. (no mechanisms)
Br
1. Mg, Ether
2. CH3CHO, H3O+
A
G
Cold KMnO4
neutral
H2O
B
SOCI₂
elimination
reaction
H+, H₂O
heat
PCC
E
(CH3)2S
FL
0
NaBH4
5) What reagents/conditions are necessary to carry out the reaction shown below?
HH-
H H
A. Heat
B. Light
C. Acid
D. Base
The reaction is
Photochemical cyclization
which involves light
to form a fused
ring
6) What reagents would you need to use to perform the following transformation?
Motory pup
on ortho or paren
acco
500-
a. 1) AIC, CICH, 2) KMnO4 3) NH3
b. 1) KMnO42) AICI, CICH3 3) NH3
1) AICL, CICH, 2) NBS 3) NH3
d. 1) NBS 2) NH, 3) NaOH, H₂NNH₂
C
ALCIS
कठै
NH2
←
-reduce to
Bromine
at a Benzylic
Position
then can
be subsituted
UBS
Frida
craft alkylation
B
Br
NAS
NH3
7) Which of the following statements about the product of the electrocyclic ring
closure is correct?
CH3
H3C.
heat
A) The methyl groups are trans in the product.
B The product arose from a conrotatory ring closure.
The product contains one fewer π-bond than the starting material
D) Both A and C
E) All of the above
Chapter 3 Solutions
Chemistry: A Molecular Approach
Ch. 3 - What is the empirical formula of a compound with...Ch. 3 - Prob. 2SAQCh. 3 - Prob. 3SAQCh. 3 - Prob. 4SAQCh. 3 - Prob. 5SAQCh. 3 - Prob. 6SAQCh. 3 - Q7. Name the compound .
a) phosphorus iodide b)...Ch. 3 - Prob. 8SAQCh. 3 - Prob. 9SAQCh. 3 - Prob. 10SAQ
Ch. 3 - Q11. Determine the mass of potassium in 35.5 g of...Ch. 3 - Prob. 12SAQCh. 3 - Prob. 13SAQCh. 3 - Prob. 14SAQCh. 3 - Prob. 15SAQCh. 3 - Prob. 1ECh. 3 - Prob. 2ECh. 3 - Prob. 3ECh. 3 - Prob. 4ECh. 3 - Prob. 5ECh. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Prob. 11ECh. 3 - Prob. 12ECh. 3 - Prob. 13ECh. 3 - Prob. 14ECh. 3 - Prob. 15ECh. 3 - Prob. 16ECh. 3 - Prob. 17ECh. 3 - Prob. 18ECh. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - Prob. 21ECh. 3 - 22. Write a generic formula for each of the...Ch. 3 - 23. Determine the number of each type of atom in...Ch. 3 - Prob. 24ECh. 3 - Prob. 25ECh. 3 - 26. Write a chemical formula for each molecular...Ch. 3 - Prob. 27ECh. 3 - Prob. 28ECh. 3 - 29. Classify each compound as ionic or...Ch. 3 - 30. Classify each compound as ionic or...Ch. 3 - 31. Based on the molecular views, classify each...Ch. 3 - 32. Based on the molecular views, classify each...Ch. 3 - 33. Write a formula for the ionic compound that...Ch. 3 - Prob. 34ECh. 3 - Prob. 35ECh. 3 - Prob. 36ECh. 3 - Prob. 37ECh. 3 - 38. Name each ionic compound.
a. SnCl4
b. PbI2
c....Ch. 3 - 39. Give each ionic compound an appropriate...Ch. 3 - 40. Give each ionic compound an appropriate...Ch. 3 - Prob. 41ECh. 3 - Prob. 42ECh. 3 - Prob. 43ECh. 3 - Prob. 44ECh. 3 - Prob. 45ECh. 3 - Prob. 46ECh. 3 - Prob. 47ECh. 3 - 48. Name each molecular compound.
a. SO3
b. SO2
c....Ch. 3 - Prob. 49ECh. 3 - 50. Write the formula for each molecular...Ch. 3 - Prob. 51ECh. 3 - Prob. 52ECh. 3 - Prob. 53ECh. 3 - 54. Write the formula for each acid.
a. phosphoric...Ch. 3 - Prob. 55ECh. 3 - Use the nomenclature flowchart (Figure 3.10) to...Ch. 3 - Prob. 57ECh. 3 - Prob. 58ECh. 3 - 59. Calculate the formula mass for each...Ch. 3 - Prob. 60ECh. 3 - 61. Calculate the number of moles in each...Ch. 3 - 62. Calculate the mass of each sample.
a. 15.7 mol...Ch. 3 - 63. Determine the number of moles (of molecules or...Ch. 3 - Prob. 64ECh. 3 - Prob. 65ECh. 3 - Prob. 66ECh. 3 - 67. Calculate the mass (in g) of each sample.
a....Ch. 3 - Prob. 68ECh. 3 - 69. A sugar crystal contains approximately 1.8 ×...Ch. 3 - Prob. 70ECh. 3 - 71. Calculate the mass percent composition of...Ch. 3 - Prob. 72ECh. 3 - 73. Most fertilizers consist of...Ch. 3 - 74. Iron in the earth is in the form of iron ore....Ch. 3 - 75. Copper(II) fluoride contains 37.42% F by mass....Ch. 3 - Prob. 76ECh. 3 - 77. The iodide ion is a dietary mineral essential...Ch. 3 - 78. The American Dental Association recommends...Ch. 3 - 79. Write a ratio showing the relationship between...Ch. 3 - Prob. 80ECh. 3 - Prob. 81ECh. 3 - Prob. 82ECh. 3 - Prob. 83ECh. 3 - 84. Calculate the mass (in kilograms) of chlorine...Ch. 3 - 87. A chemist decomposes samples of several...Ch. 3 - 88. A chemist decomposes samples of several...Ch. 3 - 89. Calculate the empirical formula for each...Ch. 3 - 90. Calculate the empirical formula for each...Ch. 3 - 91. The elemental mass percent composition of...Ch. 3 - 92. The elemental mass percent composition of...Ch. 3 - 93. A 0.77-mg sample of nitrogen reacts with...Ch. 3 - 94. A 45.2-mg sample of phosphorus reacts with...Ch. 3 - The empirical formula and molar mass of several...Ch. 3 - 96. From the given molar mass and empirical...Ch. 3 - 97. Combustion analysis of a hydrocarbon produces...Ch. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - 100. Tartaric acid is the white, powdery substance...Ch. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - 104. When iron rusts, solid iron reacts with...Ch. 3 - Prob. 103ECh. 3 - Prob. 104ECh. 3 - Prob. 105ECh. 3 - 108. Write the balanced chemical equation for each...Ch. 3 - Prob. 107ECh. 3 - Prob. 108ECh. 3 - 111. Balance each chemical equation.
a. CO2(g) +...Ch. 3 - 112. Balance each chemical equation.
a. Na2S(aq) +...Ch. 3 - Prob. 111ECh. 3 - Prob. 112ECh. 3 - Prob. 113ECh. 3 - Prob. 114ECh. 3 - Prob. 115ECh. 3 - Prob. 116ECh. 3 - Prob. 117ECh. 3 - Prob. 118ECh. 3 - 121. How many molecules of ethanol (C2H5OH) (the...Ch. 3 - 122. A drop of water has a volume of approximately...Ch. 3 - 123. Determine the chemical formula of each...Ch. 3 - 124. Determine the chemical formula of each...Ch. 3 - Prob. 123ECh. 3 - Prob. 124ECh. 3 - 127. A metal (M) forms a compound with the formula...Ch. 3 - Prob. 126ECh. 3 - 129. Estradiol is a female sexual hormone that is...Ch. 3 - 130. Fructose is a common sugar found in fruit....Ch. 3 - 131. Combustion analysis of a 13.42-g sample of...Ch. 3 - 132. Estrone, which contains only carbon,...Ch. 3 - 133. Epsom salts is a hydrated ionic compound with...Ch. 3 - 134. A hydrate of copper(II) chloride has the...Ch. 3 - Prob. 133ECh. 3 - Prob. 134ECh. 3 - Prob. 135ECh. 3 - Prob. 136ECh. 3 - Prob. 137ECh. 3 - Prob. 138ECh. 3 - Prob. 139ECh. 3 - 142. A phosphorus compound that contains 34.00%...Ch. 3 - Prob. 141ECh. 3 - 144. Phosphorus is obtained primarily from ores...Ch. 3 - Prob. 143ECh. 3 - Prob. 144ECh. 3 - Prob. 145ECh. 3 - Prob. 146ECh. 3 - Prob. 147ECh. 3 - Prob. 148ECh. 3 - 151. Lead is found in Earth's crust as several...Ch. 3 - 152150. A 2.52-g sample of a compound containing...Ch. 3 - 153. A compound of molar mass 229 g/mol contains...Ch. 3 - Prob. 152ECh. 3 - Prob. 153ECh. 3 - Prob. 154ECh. 3 - 157. When molecules are represented by molecular...Ch. 3 - Prob. 156ECh. 3 - Prob. 157ECh. 3 - Prob. 158ECh. 3 - 161. Without doing any calculations, arrange the...Ch. 3 - Q60. Element A is an atomic element, and element...
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