Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 28, Problem 28.19P
Interpretation Introduction

(a)

Interpretation:

The allowed and reasonable sigmatropic reaction can account for the given reaction is to be stated.

Concept introduction:

The pericyclic reactions in which one sigma bond is converted to another sigma bond within the uncatalyzed intramolecular reaction are known as sigmatropic reactions. In this rearrangement, the shifting of one substituent from one region of a π system to another region takes place simultaneously.

Interpretation Introduction

(b)

Interpretation:

The expected product from a similar reaction of 2,3dimethyl1,3cyclopentadiene is to be stated.

Concept introduction:

The pericyclic reactions in which one sigma bond is converted to another sigma bond within the uncatalyzed intramolecular reaction are known as sigmatropic reactions. In this rearrangement, the shifting of one substituent from one region of a π system to another region takes place simultaneously.

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