LL ORG CHEM
6th Edition
ISBN: 9781264840083
Author: SMITH
Publisher: MCG
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Question
Chapter 26.6, Problem 13P
Interpretation Introduction
(a)
Interpretation: The given Haworth projection is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively.
Interpretation Introduction
(b)
Interpretation: The given Haworth projection is to be converted into its acyclic form.
Concept introduction: The structural representation of sugar molecule in cyclic form is known as Haworth projection. In Fischer projection formula, the horizontal and vertical line represents the bonds that are present above and below the plane, respectively.
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Problem 5.16
Label each stereogenic center as R or S.
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Problem 5.20
Label the two stereogenic centers in
dB
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stereoisomers.
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each compound and draw all possible
CI
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Br
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B.
Problem 5.21
Compounds E and F are two isomers of 2,3-dibromopentane drawn in staggered
conformations. Which compounds (A-D) in Figure 5.8 are identical to E and F?
im et wihr boe A
mot
Br
omin oldne
Br
F
Br
Draw the products formed when each diene is treated with one equivalent of HCI.
a.
b.
d.
Chapter 26 Solutions
LL ORG CHEM
Ch. 26.2 - Prob. 1PCh. 26.2 - Prob. 2PCh. 26.2 - Label each stereogenic center as R or S. a. b. c....Ch. 26.2 - Convert the ball-and-stick model to a Fischer...Ch. 26.2 - Prob. 5PCh. 26.2 - Prob. 6PCh. 26.3 - Prob. 7PCh. 26.3 - Prob. 8PCh. 26.4 - Prob. 9PCh. 26.4 - Prob. 10P
Ch. 26.6 - Prob. 11PCh. 26.6 - Prob. 12PCh. 26.6 - Prob. 13PCh. 26.6 - Prob. 14PCh. 26.6 - Prob. 15PCh. 26.7 - Prob. 16PCh. 26.7 - Draw a stepwise mechanism for the following...Ch. 26.7 - Prob. 18PCh. 26.8 - Prob. 19PCh. 26.9 - Prob. 20PCh. 26.9 - Prob. 21PCh. 26.9 - Draw the products formed when D-arabinose is...Ch. 26.9 - Prob. 23PCh. 26.10 - Prob. 24PCh. 26.10 - Prob. 25PCh. 26.10 - Prob. 26PCh. 26.10 - Prob. 27PCh. 26.11 - Prob. 28PCh. 26.11 - Prob. 29PCh. 26.12 - Prob. 30PCh. 26.12 - Prob. 31PCh. 26.13 - Prob. 32PCh. 26.13 - Prob. 33PCh. 26.13 - Problem-28.35
Draw the structures of the...Ch. 26.13 - Prob. 35PCh. 26 - 28.37 Convert each ball-and-stick model to a...Ch. 26 - Prob. 37PCh. 26 - Prob. 38PCh. 26 - 28.40 Convert each compound to a Fischer...Ch. 26 - Prob. 40PCh. 26 - Prob. 41PCh. 26 - 28.43 Draw a Haworth projection for each compound...Ch. 26 - Prob. 43PCh. 26 - 28.45 Draw both pyranose anomers of each...Ch. 26 - Prob. 45PCh. 26 - 28.50 Draw the products formed when D-altrose is...Ch. 26 - 28.58 Draw a stepwise mechanism for the following...Ch. 26 - Prob. 62PCh. 26 - Prob. 63PCh. 26 - Prob. 64PCh. 26 - Prob. 65PCh. 26 - Prob. 66PCh. 26 - Prob. 67PCh. 26 - Prob. 68PCh. 26 - Prob. 69PCh. 26 - Prob. 70P
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- Give the IUPAC name for each compound, including the R, S designation for each stereogenic center. In a. b. C.arrow_forwardDraw a stepwise mechanism and all stereoisomers formed following reaction.arrow_forwardProblem 5.2 Classify each pair of compounds as constitutional isomers or stereoisomers. a. and and он 020st geabe AA go Aon e 2o3 С. and d. and b.arrow_forward
- Problem 5.24 Draw a meso compound for each of the following molecules. a. Br CI Br b. HO OH c. H₂N NH₂arrow_forwardWhich heterocycles are aromatic? a. d. b.arrow_forwardProblem 5.22 Draw all the possible stereoisomers for each compound, and label pairs of enantiomers hen and diastereomers. Ust a. OH fevidas OH b. CIto snelg e vil OHarrow_forward
- Draw the product of each Diels-Alder reaction and indicate the stereochemistry at all stereogenic centers. A a. b.arrow_forwardConvert each Haworth projection to its acyclic form.arrow_forwardDraw the products formed in each reaction sequence. a. b. CI [1] Ph3P Br [2] BuLi H [3] [1] Ph3P [2] BuLi [3] Harrow_forward
- Captopril is a drug used to treat high blood pressure and congestive heart failure. a.Designate each stereogenic center as R or S. b.Draw the enantiomer of captopril. c.What product is formed when captopril is treated with one equivalent of NaH? d.What product is formed when captopril is treated with two equivalents of NaH?arrow_forwardSaquinavir (trade name Invirase) is a protease inhibitor, used to treat HIV (human immunodeficiency virus). a.Locate all stereogenic centers in saquinavir, and label each stereogenic center as R or S. b.Draw the enantiomer of saquinavir. c.Draw a diastereomer of saquinavir. d.Draw a constitutional isomer that contains at least one different functional group.arrow_forwardDraw a stepwise mechanism for the following isomerization.arrow_forward
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