Organic Chemistry (9th Edition)
9th Edition
ISBN: 9780321971371
Author: Leroy G. Wade, Jan W. Simek
Publisher: PEARSON
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Chapter 26.2A, Problem 26.3P
Interpretation Introduction
Interpretation: The mechanism for branching in free radical polymerisation of styrene is to be shown and the type of aliphatic hydrogen which is most likely to be abstracted is to be explained.
Concept Introduction: Free radical polymerisation is the polymerisation in which
To determine: The mechanism of the given reaction; also the type of hydrogen which is most likely to be abstracted in the given reaction.
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Chapter 26 Solutions
Organic Chemistry (9th Edition)
Ch. 26.2A - Show the intermediate that would result if the...Ch. 26.2A - Prob. 26.2PCh. 26.2A - Prob. 26.3PCh. 26.2B - Prob. 26.4PCh. 26.2B - Prob. 26.5PCh. 26.2B - Chain branching occurs in cationic polymerization...Ch. 26.2C - Prob. 26.7PCh. 26.2C - Prob. 26.8PCh. 26.2C - Chain branching is not as common with anionic...Ch. 26.3 - Prob. 26.10P
Ch. 26.5 - Prob. 26.11PCh. 26.6 - Prob. 26.12PCh. 26.7A - Prob. 26.13PCh. 26.7B - Prob. 26.14PCh. 26.7B - Prob. 26.15PCh. 26.7C - a. Propose a mechanism for the reaction of...Ch. 26.7C - Prob. 26.17PCh. 26.7D - Prob. 26.18PCh. 26.7D - Prob. 26.19PCh. 26.7D - Prob. 26.20PCh. 26 - Prob. 26.21SPCh. 26 - Prob. 26.22SPCh. 26 - Poly(trimethylene carbamate) is used in...Ch. 26 - Prob. 26.24SPCh. 26 - Urylon fibers are used in premium fishing nets...Ch. 26 - Prob. 26.26SPCh. 26 - Prob. 26.27SPCh. 26 - Polyoxymethylene (polyformaldehyde) is the tough,...Ch. 26 - Prob. 26.29SPCh. 26 - Prob. 26.30SPCh. 26 - Prob. 26.31SPCh. 26 - Prob. 26.32SPCh. 26 - Prob. 26.33SPCh. 26 - Prob. 26.34SPCh. 26 - The polyester named Lactomer is an alternating...Ch. 26 - Prob. 26.36SP
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- Radical polymerization of styrene gives a linear polymer. Radical polymerization of a mixture of styrene and 1,4-divinylbenzene gives a cross-linked network polymer of the type shown in Figure 29.1. Show by drawing structural formulas how incorporation of a few percent of 1,4-divinylbenzene in the polymerization mixture gives a cross-linked polymer.arrow_forwardChain branching occurs in cationic polymerization much as it does in free-radical polymerization. Propose a mechanism to show how branching occurs in the cationic polymerization of styrene. Suggest why isobutylene might be a better monomer for cationic polymerization than styrene.arrow_forward16 The molecular weight of polymer when styrene is polymerized in benzene is 400,000. With all other conditions the same, addition of 4.23 mg/L of n-butyl mercaptan de- creases the molecular weight to 85,000. What concentration (mg/L) of n-butyl mer- captan will give a molecular weight of 50,000 (other conditions remaining the same) ? [Ans. 8 mg L-l]arrow_forward
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- a) Draw (ACTUALLY DRAW THE STRUCTURE) the polymer structure that would result from the following polymerization. Show correct parantheses placement, as well as any initiator/terminating end groups. b) What would happen to the dispersity of this polymer if the quantity of AIBN was increased to at or above the quantity of chain transfer agent? S= Et₂N S' CN مية 2% AIBNarrow_forwardDraw a structural formula of the polymer resulting from base-catalyzed polymerization of each compound. Would you expect the polymers to be optically active? (S)-(+)-lactide is the dilactone formed from two molecules of (S)-(+)-lactic acid.arrow_forwardBased on IR spectra of "Free Radical Polymerization of Styrene" experiment, how well the reaction workedarrow_forward
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