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GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- When 85.0 mL of 0.250 M Ba(OH)2 solution is added to 85.00 mL of 0.250 M Al (NO3)3 solution, a white gelatinous precipitate of Al(OH)3; is formed. Assuming 100% yield, (a) what mass (in grams) of Al(OH)3 is formed? (b) what is the molarity of each of the ions Ba2+, OH-, Al3+, NO3- in the resulting solution?arrow_forwardUse the appropriate tables to calculate H for (a) the reaction between MgC03(s) and a strong acid to give Mg2+(aq), CO2(g), and water. (b) the precipitation of iron(III) hydroxide from the reaction between iron(III) and hydroxide ions.arrow_forwardLead poisoning has been a hazard for centuries. Some scholars believe that the decline of the Roman Empire can be traced, in part, to high levels of lead in water from containers and pipes, and from wine that was stored in leadglazed containers. If we presume that the typical Roman water supply was saturated with lead carbonate, PbCO3 (Ksp = 7.4 1014), how much lead will a Roman ingest in a year if he or she drinks 1 L/day from the container?arrow_forward
- Calculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardAccording to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?arrow_forwardGiven HFH+(aq)+F(aq)Ka=6.9104HF(aq)+F(aq)H2(aq)K=2.7 calculate K for the reaction 2HF(aq)H+(aq)+HF2(aq)arrow_forward
- When carbon dioxide dissolves in water it reacts to produce carbonic acid, H2CO3(aq), which can ionize in two steps. H2CO3(aq)HCO3(aq)+H+(aq)Kc1=4.2107HCO3(aq)CO32(aq)+H+(aq)Kc2=4.81011 Calculate the equilibrium constant for the reaction H2CO3(aq)CO32(aq)+2H+(aq)arrow_forwardCalculate the molarity of AgNO3 in a solution prepared by dissolving 1.44 g AgNO3 in enough water to form 1.00 L solution.arrow_forwardThe Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forward
- Atomic masses can be determined by electrolysis. In one hour, a current of 0.600 A deposits 2.42 g of a certain metal, M, which is present in solution as M+ ions. What is the atomic mass of the metal?arrow_forwardGold is isolated from rocks by reaction with aqueouscyanide, CN-: 4 Au(s) + 8 NaCN(aq) + O2(g) + H2O(l)-------->4 Na[Au(CN)2](aq) + 4 NaOH(aq). (a) Which atoms fromwhich compounds are being oxidized, and which atomsfrom which compounds are being reduced? (b) The[Au(CN)2]- ion can be converted back to Au(0) by reactionwith Zn(s) powder. Write a balanced chemical equationfor this reaction. (c) How many liters of a 0.200 M sodiumcyanide solution would be needed to react with 40.0 kg ofrocks that contain 2.00% by mass of gold?arrow_forwardUse the solubility rules to predict whether the following ionic compounds are soluble in water: (a) Li 2CO 3; (b) MgCO 3; (c) KBr; (d) PbSO 4; (e) CaCl 2; (f) MgCl 2.arrow_forward
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