Student Study Guide and Solutions Manual for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
8th Edition
ISBN: 9781305864504
Author: Brent L. Iverson, Sheila Iverson
Publisher: Cengage Learning
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Chapter 23.5, Problem FQ
Interpretation Introduction
Interpretation:
Name of the organic
Concept introduction:
An
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How can the structure of the following molecule be changed in order to make it more acidic?
A. Replacing the CI substituent with OH
8. Moving the CI substituent to the C position
C. Moving the CI substituent to the C position
D. Replacing the CI substituent with an NH₂
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The most common reaction involving the carboxylic acids and its derivatives is related to the presence of an acyl group.
In the structure shown below, which group corresponds to the alkyl group of the acyl structure?
A. n-propyl group
8. Chloro group
C. Isobutyl group
D. Carbonyl group
An aldehyde commonly exhibits a nucleophilic addition type of reaction. When a nucleophile attacks a carbonyl carbon,
what happens to the oxygen atom in the structure? Refer to the structure below.
A. Oxygen atom obtains a net negative charge.
B. Oxygen atom becomes more electronegative.
C. Oxygen atom acts as the new electrophile.
D. Oxygen atom transforms to an alkoxide group.
1. There is one compound (that contains only one carbonyl group) that gives both a positive iodoform test and a positive Tollens’ test. This compound is not included in the table of unknowns. Use your knowledge of the test to predict this compound and draw it. Hint: the molecular weight of the compound is less than 60
2. Draw the structure of a molecule, an unknown aldehyde or ketone listed in the tables, that would show a negative Tollens’ test and a negative iodoform test. There is more than one correct answer. Draw one!
3. You acquired the following data: bp 173 °C; – Tollens’, + iodoform tests; semicarbazone mp 105 °C. You are very confident that your unknown is 2- octanone. Data is spot on, excluding the semicarbazone mp. You suspect the suppressed mp is due to wet crystals. What process or technique (other than continued oven drying) can help you obtain more pure semicarbazone and thus a more accurate mp for comparison? Please write answer in box at right.
Chapter 23 Solutions
Student Study Guide and Solutions Manual for Brown/Iverson/Anslyn/Foote's Organic Chemistry, 8th Edition
Ch. 23.1 - Prob. 23.1PCh. 23.2 - Prob. 23.2PCh. 23.2 - Prob. 23.3PCh. 23.2 - Prob. 23.4PCh. 23.5 - Prob. 23.5PCh. 23.5 - Prob. AQCh. 23.5 - What is the hybridization of the nitrogen in...Ch. 23.5 - Prob. CQCh. 23.5 - The pKas of the conjugate acids of aniline and...Ch. 23.5 - Prob. EQ
Ch. 23.5 - Prob. FQCh. 23.5 - Prob. GQCh. 23.5 - Select the stronger acid from each pair of...Ch. 23.6 - Prob. 23.7PCh. 23.6 - Prob. 23.8PCh. 23.6 - Prob. 23.9PCh. 23.7 - Prob. 23.10PCh. 23.8 - Prob. 23.11PCh. 23.8 - Prob. 23.12PCh. 23.8 - Prob. 23.13PCh. 23.9 - Prob. 23.14PCh. 23.10 - In Example 23.15, you considered the product of...Ch. 23 - Prob. 23.16PCh. 23 - Prob. 23.17PCh. 23 - Prob. 23.18PCh. 23 - Prob. 23.19PCh. 23 - Prob. 23.20PCh. 23 - Prob. 23.21PCh. 23 - Prob. 23.22PCh. 23 - Account for the formation of the base peaks in...Ch. 23 - Prob. 23.24PCh. 23 - Select the stronger base from each pair of...Ch. 23 - The pKa, of the conjugate acid of morpholine is...Ch. 23 - Which of the two nitrogens in pyridoxamine (a form...Ch. 23 - Prob. 23.28PCh. 23 - Prob. 23.29PCh. 23 - Prob. 23.30PCh. 23 - Prob. 23.31PCh. 23 - Suppose you have a mixture of these three...Ch. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - Prob. 23.35PCh. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - (S)-Glutamic acid is one of the 20 amino acid...Ch. 23 - Prob. 23.39PCh. 23 - Propose a structural formula for the compound...Ch. 23 - Prob. 23.41PCh. 23 - The pyrolysis of acetic esters to give an alkene...Ch. 23 - Propose steps for the following conversions using...Ch. 23 - Show how to bring about each step in this...Ch. 23 - Show how to bring about each step in the following...Ch. 23 - Prob. 23.48PCh. 23 - Prob. 23.49PCh. 23 - Methylparaben is used as a preservative in foods,...Ch. 23 - Prob. 23.51PCh. 23 - Prob. 23.52PCh. 23 - Propose a synthesis for the systemic agricultural...Ch. 23 - Prob. 23.54PCh. 23 - Several diamines are building blocks for the...Ch. 23 - Prob. 23.56PCh. 23 - Prob. 23.57PCh. 23 - Prob. 23.58PCh. 23 - Prob. 23.59PCh. 23 - Following is a retrosynthesis for the coronary...Ch. 23 - Prob. 23.61PCh. 23 - Prob. 23.62PCh. 23 - Given this retrosynthetic analysis, propose a...Ch. 23 - Prob. 23.64PCh. 23 - Following is a series of anorexics (appetite...Ch. 23 - Prob. 23.66PCh. 23 - Prob. 23.67PCh. 23 - Show how the synthetic scheme developed in Problem...Ch. 23 - Prob. 23.69PCh. 23 - Prob. 23.70PCh. 23 - Prob. 23.71PCh. 23 - Prob. 23.72P
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