To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction. Concept introduction: Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is, Deprotonation of α carbon Attach of enolate ion with the aldehyde (nucleophilic attack) Protonation of the alkoxide ion to give aldol product

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Answer 1

Question

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

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Answer 2

Question

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

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Answer 3

Question

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

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Answer 4

Question

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

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Answer 5

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

Answer 6

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

Answer 7

Chapter 22.3, Problem 17ATS

Interpretation Introduction

Interpretation:

To explain why 2,2-dimethylbutanal does not undergo aldol addition reaction.

Concept introduction:

Aldol addition reaction means the reaction between aldehyde which has an α hydrogen to form an addition product comprising of aldehyde and alcohol group in presence of base, namely sodium hydroxide. The name Aldol stands for aldehyde and alcohol (ald for “aldehyde” and ol for “alcohol”). The three steps involved in aldol addition reaction is,

Deprotonation of α carbon

Attach of enolate ion with the aldehyde (nucleophilic attack)

Protonation of the alkoxide ion to give aldol product

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.1 - Prob. 1CC Ch. 22.1 - Prob. 2CC Ch. 22.1 - Prob. 3CC Ch. 22.1 - Prob. 1LTS Ch. 22.1 - Prob. 4PTS Ch. 22.1 - Prob. 5ATS Ch. 22.1 - Prob. 6CC Ch. 22.1 - Prob. 7CC Ch. 22.1 - Prob. 8CC Ch. 22.2 - Prob. 9CC

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Chapter 22 Solutions