Concept explainers
Devise a synthesis of each labeled compound using
a. b. c. d.
(a)
Interpretation:
The synthesis of given compound by the use of
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilc acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.75P
The synthesis of given compound by the use of
Explanation of Solution
An ester is formed by the reaction of carboxylic acid with alcohol. This reaction is known as Fischer Esterification. During this reaction, bond formation between carbon and oxygen takes place and water removes as a byproduct. In the synthesis of given compound, acetic acid is used as the source of unlabeled carbon atom and
Figure 1
The synthesis of given compound by the use of
(b)
Interpretation:
The synthesis of given compound by the use of
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilc acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.75P
The synthesis of given compound by the use of
Explanation of Solution
An ester is formed by the reaction of carboxylic acid with alcohol. This reaction is known as Fischer Esterification. During this reaction, bond formation between carbon and oxygen takes place and water removes as a byproduct. In the synthesis of given compound,
Figure 2
The synthesis of given compound by the use of
(c)
Interpretation:
The synthesis of given compound by the use of
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilc acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.75P
The synthesis of given compound by the use of
Explanation of Solution
An ester is formed by the reaction of carboxylic acid with alcohol. This reaction is known as Fischer Esterification. During this reaction, bond formation between carbon and oxygen takes place and water removes as a byproduct. In the synthesis of given compound, diethylether is first hydrolyzed to give
Figure 3
The synthesis of given compound by the use of
(d)
Interpretation:
The synthesis of given compound by the use of
Concept introduction:
The replacement or substitution of one functional group with another functional group in any chemical reaction is termed as substitution reaction. The electron rich chemical species that contains negative charge or lone pair of electrons is known as a nucleophile. In nucleophilc acyl substitution reaction, a nucleophile takes the position of a leaving group.
Answer to Problem 22.75P
The synthesis of given compound by the use of
Explanation of Solution
An ester is formed by the reaction of carboxylic acid with alcohol. This reaction is known as Fischer Esterification. During this reaction, bond formation between carbon and oxygen takes place and water removes as a byproduct. In the synthesis of given compound,
Figure 4
The synthesis of given compound by the use of
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Chapter 22 Solutions
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