Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 22, Problem 22.59QP
Interpretation Introduction
Interpretation: The Iron is the metal in hemoglobin but not the more stable
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Chapter 22 Solutions
Chemistry: Atoms First
Ch. 22.1 - Prob. 22.1WECh. 22.1 - Give oxidation numbers for the metals in (a)...Ch. 22.1 - Prob. 1PPBCh. 22.1 - Prob. 1PPCCh. 22.1 - Write the names of the following coordination...Ch. 22.1 - Give the correct name for (a) [Co(NH3)4Br2]Cl, (b)...Ch. 22.1 - Prob. 2PPBCh. 22.1 - Prob. 2PPCCh. 22.1 - Prob. 22.3WECh. 22.1 - Prob. 3PPA
Ch. 22.1 - Prob. 3PPBCh. 22.1 - Prob. 3PPCCh. 22.1 - Prob. 22.1.1SRCh. 22.1 - Prob. 22.1.2SRCh. 22.1 - Prob. 22.1.3SRCh. 22.1 - Write the correct formula for...Ch. 22.3 - Prob. 22.4WECh. 22.3 - Prob. 4PPACh. 22.3 - Prob. 4PPBCh. 22.3 - Prob. 4PPCCh. 22.3 - Prob. 22.3.1SRCh. 22.3 - Prob. 22.3.2SRCh. 22 - What distinguishes a transition metal from a main...Ch. 22 - Prob. 22.2QPCh. 22 - Prob. 22.3QPCh. 22 - Without referring to the text, write the...Ch. 22 - Write the electron configurations of the following...Ch. 22 - Prob. 22.6QPCh. 22 - Prob. 22.7QPCh. 22 - Prob. 22.8QPCh. 22 - Describe the interaction between a donor atom and...Ch. 22 - Prob. 22.10QPCh. 22 - Prob. 22.11QPCh. 22 - Prob. 22.12QPCh. 22 - Prob. 22.13QPCh. 22 - What are the systematic names for the following...Ch. 22 - Prob. 22.15QPCh. 22 - Write the formulas for each of the following ions...Ch. 22 - Prob. 22.17QPCh. 22 - Prob. 22.18QPCh. 22 - Prob. 22.19QPCh. 22 - Prob. 22.20QPCh. 22 - Prob. 22.21QPCh. 22 - Prob. 22.22QPCh. 22 - Prob. 22.23QPCh. 22 - Prob. 22.24QPCh. 22 - Prob. 22.25QPCh. 22 - Briefly describe crystal field theory.Ch. 22 - Prob. 22.27QPCh. 22 - What is the origin of color in a coordination...Ch. 22 - Prob. 22.29QPCh. 22 - Prob. 22.30QPCh. 22 - Prob. 22.31QPCh. 22 - Prob. 22.32QPCh. 22 - The absorption maximum for the complex ion...Ch. 22 - Prob. 22.34QPCh. 22 - Prob. 22.35QPCh. 22 - Prob. 22.36QPCh. 22 - Prob. 22.37QPCh. 22 - Prob. 22.38QPCh. 22 - Prob. 22.39QPCh. 22 - Prob. 22.40QPCh. 22 - The [Fe(CN)6]3 complex is more labile than the...Ch. 22 - Prob. 22.42QPCh. 22 - Prob. 22.43QPCh. 22 - Prob. 22.44QPCh. 22 - Prob. 22.45QPCh. 22 - Prob. 22.46QPCh. 22 - Prob. 22.47QPCh. 22 - Prob. 22.48QPCh. 22 - Prob. 22.49QPCh. 22 - Prob. 22.50QPCh. 22 - Prob. 22.51QPCh. 22 - Prob. 22.52QPCh. 22 - Prob. 22.53QPCh. 22 - Prob. 22.54QPCh. 22 - A student in 1895 prepared three coordination...Ch. 22 - Prob. 22.56QPCh. 22 - Prob. 22.57QPCh. 22 - Prob. 22.58QPCh. 22 - Prob. 22.59QPCh. 22 - Prob. 22.60QPCh. 22 - Prob. 22.61QPCh. 22 - Hydrated Mn2+ ions are practically colorless (see...Ch. 22 - Which of the following hydrated cations are...Ch. 22 - Prob. 22.64QPCh. 22 - Prob. 22.65QPCh. 22 - Prob. 22.66QPCh. 22 - Prob. 22.67QPCh. 22 - Prob. 22.68QPCh. 22 - Prob. 22.69QPCh. 22 - Prob. 22.70QPCh. 22 - Commercial silver-plating operations frequently...Ch. 22 - Prob. 22.72QPCh. 22 - Prob. 22.73QPCh. 22 - Prob. 22.74QPCh. 22 - Prob. 22.75QPCh. 22 - Prob. 22.76QPCh. 22 - Prob. 22.77QPCh. 22 - Prob. 22.78QPCh. 22 - Prob. 22.79QPCh. 22 - Prob. 22.80QP
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- (a) Name this coordination compound: [Ag(NH3)2]NO3. (b) Write the formula of pentaaquaisothiocyanatoiron(III) chloride.arrow_forwardThere are four iron atoms in each hemoglobin molecule. The mass percent of iron in a hemoglobin molecule is 0.35%. Estimate the molar mass of hemoglobin.arrow_forwardAn antibody with high affinity for its antigen has a Ka in the low nanomolar range. Assume an antibody binds CD34 with a K of 1.20 × 10-¹⁰ M. Calculate the CD34 concentration when Y, the fraction of binding sites occupied by the ligand, is 0.224. Calculate the CD34 concentration when Y is 0.458. Calculate the CD34 concentration when Y is 0.660. Calculate the CD34 concentration when Y is 0.80. [CD34] = [CD34] = [CD34] = [CD34] = M M M Marrow_forward
- In this pic, the nitrogen atom of the amino group is sp2 hybridized and there is a R–Br···π interaction in the complex. I would like to know if there is any relationship between them( the hybridization and the interaction)? thanksarrow_forwardAssume you determine that there are 58.00 g of oxalate and 12.27 g of iron in a 100.0 g sample of your KwFex(C2O4)y(H2O)z. What is the mass of potassium in your 100.0 g sample? Remember that iron is present in a +3 oxidation state, oxalate has a charge of -2, and potassium is used to balance the charge of the iron-oxalate complex.arrow_forwardCysteine is an amino acid with S as the donor atom. It forms complexes with Fe2*, Hg2+, Mg2+, and Zn2+. Which set of pKf assignments is CORRECT for the formation of complexes of these metals with cysteine? Fe-complex Hg-complex Mg-complex Zn-complex Set A pKf = 6.2 pKf = 14.4 pKf = <4 pKf = 9.8 %D %D %D Set B pKf = 14.4 pKf = <4 pKf = 6.2 pKf = 9.8 %3D Set C pKf = 6.2 pKf = 9.8 pKf = <4 pKf = 14.4 %3D Set D pKf = 6.2 pKf = <4 pKf =14.4 pKf = 9.8 A. Set A B. Set B C. Set C D. Set Darrow_forward
- What structural feature do hemoglobin, cytochrome c, andDoes the chlorophyll have in common?arrow_forwardWhat do you mean by coordination complexes?arrow_forwardYou are synthesizing a coordination complex using the following reaction: FeCl3 + 3K2C2O4 H₂O → K3Fe(C₂O4)3 3 H₂O + KCl To do this you have weighed out 11.113 g of K₂C₂O4 · H₂O (molar mass is 184.24 g/mol, dissolved it in 20 mL of warm DI water, and added 10.00 mL of a solution containing 0.400 g/mL of FeCl3, with a molar mass of 162.20 g/mol. 1. How many moles of K₂C₂O4 H₂O are present? 2. How many moles of FeCl3 are present? 3. Calculate the theoretical yield in grams. The molar mass of the product is 491.2 g/mol.arrow_forward
- The equilibrium constant of the reaction in aqueous solution is K = 5.00. CH3Hg(glutathione)+(aq)+cysteine(aq)CH3Hg(cysteine)+(aq)+glutathione(aq) a) Calculate the equilibrium concentration of cysteine if we start with a 1.204 mM solution of cysteine and a 1.204 mM solution of CH3Hg(glutathione)+. b) Calculate the equilibrium concentrations of glutathione under the same conditions.arrow_forwardSix cyanide ions (CN—) form with an iron(III) ion to form a complex ion, so what is the net charge of the complex?arrow_forward>Hemoglobin exists in two predominant forms in our bodies. One form, known as oxyhemoglobin, has O2 bound to the iron and the other, known as deoxyhemoglobin, has a water molecule bound instead. Oxyhemoglobin is a low-spin complex that gives arterial blood its red color, and deoxyhemoglobin is a high-spin complex that gives venous blood its darker color. Explain these observations in terms of crystal field splitting. Would you categorize O2 as a strong- or weak-field ligand?arrow_forward
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