Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 2.10, Problem 45P
a. At what pH is the concentration of a compound, with a pKa = 8.4. 100 times greater in its acidic form than in its basic form?
b. At what pH is 50% of a compound, with a pKa = 7.3 in its basic form?
c. At what pH is the concentration of a compound, with a pKa = 4.6, 10 times greater in its basic form than in its acidic form?
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At what pH is 50% of a compound, with a pKa = 7.3, in its basic form?
At what pH will the concentration of a compound with a pK, 8,4 be 100 tímes greater in ita acidic form than in its basic form?
Express your answer using one decimal place.
pH= 7.9
At what pH will 50% of a compound with a pK, = 7.6 be in its basic form?
Express your answer using one decimal place.
pH =
At what pH will the concentration of a compound with a pK = 4.6 be 10 times greater in its basic form than in its acidic form?
Express your answer using one decimal place.
pH =
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Danunet Anenr
1. What is the pH of a 0.2 M acetic acid solution where the Ka for acetic acid is 1.33 x 10-5 M.
2. What is the pH of a 0.1 M formic acid solution where the pka for formic acid is 3.77.
Chapter 2 Solutions
Organic Chemistry (8th Edition)
Ch. 2.1 - Which of the following are not acids? CH3COOH CO2...Ch. 2.1 - Consider the following reaction: a. What is the...Ch. 2.1 - Draw the products of the addbase renc1 ion when a....Ch. 2.1 - a. What is the conjugate acid of each or the...Ch. 2.2 - a. Which is a stronger acid: one with a pKa of 5.2...Ch. 2.2 - An acid has a Ka of 4.53 106 in water. What is...Ch. 2.2 - Prob. 7PCh. 2.2 - Antacids are compounds that neutralize stomach...Ch. 2.2 - Are the following body fluids acidic or basic? a....Ch. 2.3 - Draw the conjugate acid of each of the following:...
Ch. 2.3 - a. Write an equation showing CH3OH reacting as an...Ch. 2.3 - Estimate the pKa values of the following...Ch. 2.3 - a. Which is a stronger base: CH3COO or HCOO? (The...Ch. 2.3 - Using the pKa values in Section 2.3, rank the...Ch. 2.4 - Prob. 15PCh. 2.5 - a. For each of the acid-base reactions in Section...Ch. 2.5 - Ethyne has a pKa value of 25, water has a pKa...Ch. 2.5 - Which of the following bases can remove a proton...Ch. 2.5 - Calculate the equilibrium constant for the...Ch. 2.6 - Rank the ions (CH3, NH2, HO, and F) from most...Ch. 2.6 - Rank the carbanions shown in the margin from most...Ch. 2.6 - Which is the stronger acid?Ch. 2.6 - Prob. 23PCh. 2.6 - What reaction in Problem 23 has the smallest...Ch. 2.6 - Rank the halide ions (F, Cl, Br, and l) from...Ch. 2.6 - a. Which is more electronegative, oxygen or...Ch. 2.6 - Which is a stronger acid? a. HCl or HBr b....Ch. 2.6 - a. Which of the halide ions (F, Cl, Br, and l) is...Ch. 2.6 - Which is a stronger base? (The potential maps in...Ch. 2.7 - What is a stronger acid? a. CH3OCH2CH2OH or...Ch. 2.7 - Rank the following compounds from strongest add to...Ch. 2.7 - What is a stronger base?Ch. 2.8 - For each of the following compounds, indicate the...Ch. 2.8 - Prob. 35PCh. 2.8 - Which is a stronger acid? Why?Ch. 2.8 - Fosamax (shown on the previous page) has six...Ch. 2.9 - Using the table of pKa values given in Appendix I,...Ch. 2.10 - For each of the following compounds (here shown in...Ch. 2.10 - As long as the pH is not less than _______, at...Ch. 2.10 - a. Indicate whether a protonated amine (RN+H3)...Ch. 2.10 - A naturally occurring amino acid such as alanine...Ch. 2.10 - a. At what pH is the concentration of a compound,...Ch. 2.10 - For each of the following compounds, indicate the...Ch. 2.10 - Given the data in Problem 47: a. What pH would you...Ch. 2.11 - Write the equation that shows how a buffer made by...Ch. 2.12 - Draw the products of the following react ions. Use...Ch. 2.12 - What product are formed when each of the following...Ch. 2 - Which is a stronger base? a. HS or HO b. CH3O or...Ch. 2 - According to the explanations by Lewis, if a...Ch. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - a. Rank the following carboxylic acids from...Ch. 2 - Prob. 57PCh. 2 - For the following compound. a. draw its conjugate...Ch. 2 - Rank the following compounds from strongest to...Ch. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - A single bond between two carbons with different...Ch. 2 - For each compound, indicate the atom that is most...Ch. 2 - a. Given the Ka values, estimate the pKa value of...Ch. 2 - Tenormin, a member of the group of drugs known as...Ch. 2 - From which of the following compounds can HO...Ch. 2 - a. For each of the following pairs of reactions,...Ch. 2 - Prob. 69PCh. 2 - Which is a stronger acid? a. b. c. d.Ch. 2 - Prob. 71PCh. 2 - Prob. 72PCh. 2 - Given that pH+ pOH = 14 and that the concentration...Ch. 2 - How could you separate a mixture of the following...Ch. 2 - Prob. 75PCh. 2 - a. If an add with a pKa of 5.3 is in an aqueous...Ch. 2 - Calculate the pH values of the following...Ch. 2 - Prob. 1PCh. 2 - Prob. 2PCh. 2 - Prob. 3PCh. 2 - Which of the reactions in Problem 3 favor...Ch. 2 - Prob. 5PCh. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Which is the stronger acid? a. ClCH2CH2OH or...Ch. 2 - Prob. 9PCh. 2 - Prob. 10PCh. 2 - Which is a more stable base? Remembering that the...Ch. 2 - Which is the Stronger acid?Ch. 2 - Prob. 13PCh. 2 - a. Draw the structure of (CH3COOH (pKa = 4.7) at...
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- How does the pKa of an acid change as very electronegative atoms (such as Cl) are added to the acid structure? (Does pKa increase or decrease?) How does the strength of the acid vary (increase or decrease)? Which acid below would you expect to be the stronger acid?arrow_forward3. Calculate the pH of the following solutions. Hint: some parts should require very little math! a. A 0.010 M solution of an acid that completely dissociates in solution. b. A 0.010 M solution of an acid that's conjugate base has a pk of 8.2. c. A solution that's comprised of 75% acid and 25% conjugate base with a Ka = 1.4 x 10-4 d. A 0.100 M solution of sodium hydroxide.arrow_forwardConsider two acids: C,H5CO,H (benzoic acid, pK = 4.2) and HCO,H (formic acid, pK=3.8). Which acid is the stronger acid? Select the single best answer. formic acid benzoic acidarrow_forward
- Which of the following is true about acids and bases? A. When bases ionize, they donate protons. B. Strong acids and bases are completely ionized in dilute aqueous solutions. C. The dissociation constant of a strong acid is lower than that for a weak acid. D. The pKa of a strong acid will be higher than that for a weak acid.arrow_forwardPhenolphthalein has a pKa of 9.7. It is colorless in its acid form and pink in its basic form. For each of the values of pH, calculate [In-]>[HIn] and predict the color of a phenolphthalein solution. a. pH = 2.0 b. pH = 5.0 c. pH = 8.0 d. pH = 11.0arrow_forwardAnother way to express acid strength is by using pk b:pK a =−logK a Another way to express base strength is by using pK b pK b =−logK b A new potential heart medicine, code-named X-281, is being tested by a pharmaceutical company, Pharma-pill. As a research technician at Pharma-pill, you are told that X-281 is a monoprotic weak acid, but because of security concerns, the actual chemical formula must remain top secret. The company is interested in the drug's K a value because only the dissociated form of the chemical is active in preventing cholesterol buildup in arteries.To find the pK a of X-281, you prepare a 0.079 M M test solution of X-281 at 25.0 ∘ C The pH of the solution is determined to be 3.00. What is the pK a of X-281?arrow_forward
- A 0.480 M solution is made with the compound shown below. I. What class of acid or base is this compound? O Carboxylic acid O Conjugate of a carboxylic acid ○ Oxyacid O Conjugate base of an oxyacid O Amine O Conjugate acid of an amine II. What would be the pH of this solution if the acid form has a pKa = 5.15arrow_forwardThe table below contains the pKa values of four weak acids. Which acid is the weakest? HF 3.14 HNO2 3.39 H2SO3 1.81 H2CO3 6.37arrow_forwardIf X is a stronger weak acid than Y, which of the following is true? Both X and Y have pOH values less than 7 The pKa value of X is higher than the pKa value of Y The conjugate base of Y is stronger than the conjugate base of X The conjugate acid of X is weaker than the conjugate acid of Yarrow_forward
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