Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 2, Problem 68P
Interpretation Introduction
Interpretation:
Whether the carbonic acid/bicarbonate buffer is better at neutralizing excess acid or base and maintains the
Concept Introduction:
Important formulae regarding acid-base concepts are:
Henderson-Hasselbalch equation
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Chapter 2 Solutions
Organic Chemistry
Ch. 2.1 - Which of the following are not acids? CH3COOH CO2...Ch. 2.1 - Draw the products of the addbase renc1 ion when a....Ch. 2.1 - a. What is the conjugate acid of each or the...Ch. 2.2 - a. Which is a stronger acid: one with a pKa of 5.2...Ch. 2.2 - An acid has a Ka of 4.53 106 in water. What is...Ch. 2.2 - Prob. 6PCh. 2.2 - Antacids are compounds that neutralize stomach...Ch. 2.2 - Are the following body fluids acidic or basic? a....Ch. 2.3 - Draw the conjugate acid of each of the following:...Ch. 2.3 - a. Write an equation showing CH3OH reacting as an...
Ch. 2.3 - Estimate the pKa values of the following...Ch. 2.3 - a. Which is a stronger base: CH3COO or HCOO? (The...Ch. 2.3 - Using the pKa values in Section 2.3, rank the...Ch. 2.4 - Prob. 14PCh. 2.5 - a. For each of the acid-base reactions in Section...Ch. 2.5 - Ethyne has a pKa value of 25, water has a pKa...Ch. 2.5 - Which of the following bases can remove a proton...Ch. 2.5 - Calculate the equilibrium constant for the...Ch. 2.6 - Rank the ions (CH3, NH2, HO, and F) from most...Ch. 2.6 - Rank the carbanions shown in the margin from most...Ch. 2.6 - Which is the stronger acid?Ch. 2.6 - Prob. 22PCh. 2.6 - Rank the halide ions (F, Cl, Br, and l) from...Ch. 2.6 - a. Which is more electronegative, oxygen or...Ch. 2.6 - Which is a stronger acid? a. HCl or HBr b....Ch. 2.6 - a. Which of the halide ions (F, Cl, Br, and l) is...Ch. 2.6 - Prob. 27PCh. 2.7 - What is a stronger acid? a. CH3OCH2CH2OH or...Ch. 2.7 - Prob. 29PCh. 2.7 - What is a stronger base?Ch. 2.8 - Fosamax (shown on the previous page) has six...Ch. 2.8 - Which is a stronger acid? Why?Ch. 2.8 - Prob. 34PCh. 2.9 - Using the table of pKa values given in Appendix I,...Ch. 2.10 - Prob. 36PCh. 2.10 - As long as the pH is not less than _______, at...Ch. 2.10 - A naturally occurring amino acid such as alanine...Ch. 2.10 - For each of the following compounds, indicate the...Ch. 2.11 - Write the equation that shows how a buffer made by...Ch. 2.12 - Draw the products of the following react ions. Use...Ch. 2.12 - What product are formed when each of the following...Ch. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - Which is a stronger base? a. HS or HO b. CH3O or...Ch. 2 - According to the explanations by Lewis, if a...Ch. 2 - a. Rank the following carboxylic acids from...Ch. 2 - Prob. 51PCh. 2 - For the following compound. a. draw its conjugate...Ch. 2 - Rank the following compounds from strongest to...Ch. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - a. Rank the following alcohols from strongest to...Ch. 2 - For each compound, indicate the atom that is most...Ch. 2 - a. Given the Ka values, estimate the pKa value of...Ch. 2 - A single bond between two carbons with different...Ch. 2 - Tenormin, a member of the group of drugs known as...Ch. 2 - From which of the following compounds can HO...Ch. 2 - a. For each of the following pairs of reactions,...Ch. 2 - Prob. 63PCh. 2 - Which is a stronger acid? a. b. c. d.Ch. 2 - Prob. 65PCh. 2 - Given that pH+ pOH = 14 and that the concentration...Ch. 2 - How could you separate a mixture of the following...Ch. 2 - Prob. 68PCh. 2 - a. If an add with a pKa of 5.3 is in an aqueous...Ch. 2 - Calculate the pH values of the following...Ch. 2 - Prob. 1PCh. 2 - Prob. 2PCh. 2 - Prob. 3PCh. 2 - Which of the reactions in Problem 3 favor...Ch. 2 - Prob. 5PCh. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Which is the stronger acid? a. ClCH2CH2OH or...Ch. 2 - Prob. 9PCh. 2 - Prob. 10PCh. 2 - Which is a more stable base? Remembering that the...Ch. 2 - Which is the Stronger acid?Ch. 2 - Prob. 13PCh. 2 - a. Draw the structure of (CH3COOH (pKa = 4.7) at...
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- The pKa of acetic acid is 4.74. The conjugate base of acetic acid (CH3COOH) is sodium acetate (CH3COONa). One has two stock solutions. One is 0.10 M in acetic acid and the other is 0.2M in sodium acetate. If one mixes 200 Ml of the acetic acid solution with 100 mL of the sodium acetate solution, what would be the final pH?arrow_forwardAcetic acid buffer system responds to the addition of OH- ions. How would I write the equation showing the response of the acid?arrow_forwardHow can I write a equation showing how acetic acid buffer system responds to the addition of H3O+ ions?arrow_forward
- Citric acid, a triprotic acid, has 3 pKa values (3.128, 4.761, and 6.396). What is the pKb of trisodium citrate? 1.34 x 10–11 7.604 10.872 9.239arrow_forward3. The pH of the given solution of lactic acid and lactate is 4.30. Calculate the pKa of lactic acid, when the concentration of lactic acid and lactate are 0.020 M and 0.073 M respectively.arrow_forwardWhat is the purpose of the acetate buffer?arrow_forward
- Write the values of Y and X. H2SO4 CH3CH=CH2 + H2O CH;CH-CH2 H HỌ 2-propanol an alcohol The pKa of a protonated alcohol is about -2.5, and the pKa of an alcohol is about 15. Therefore, as long as the pH of the solution is greater than Y and less than X, more than 50% of 2-propanol will be in its neutral, nonprotonated form. Express your answers using two significant figures separated by a comma. AX中 Y, X = %3|arrow_forwardA 0.512 g sample of CaCO3 is dissolved in 12 M HCl and the mixture is diluted to 250 mL. How many moles of CaCO3 are used? What is the [Ca2+] in the 250 mL solution? How many moles of Ca2+ are in a 25 mL sample of the 250 mL solution?arrow_forwardThe pKa of acetic acid, HC2H3O2 is 4.58. A buffer solution was made using an unspecified amount of acetic acid and 0.4 moles of NaC2H3O2 in enough water to make 1.87 liters of solution. It's pH was measured as 3.11. How many moles of HC2H3O2 were used? Report answer with 2 places past the decimal point.arrow_forward
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