General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 2, Problem 2.59SP
What is the Heisenberg uncertainty principle, and how does it affect our description of atomic structure?
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Chapter 2 Solutions
General Chemistry: Atoms First
Ch. 2.1 - What is the frequency of a gamma ray with = 3.56 ...Ch. 2.1 - What is the wavelength in meters of an FM radio...Ch. 2.1 - Two electromagnetic waves are represented below....Ch. 2.2 - The Balmer equation can be extended beyond the...Ch. 2.2 - What is the longest-wavelength line in nanometers...Ch. 2.2 - What is the shortest-wavelength line in nanometers...Ch. 2.3 - What is the energy in kilojoules per mole of...Ch. 2.3 - The biological effects of a given dose of radiant...Ch. 2.3 - The work function of zinc metal is 350 kJ/mol....Ch. 2.3 - What is the work function of nickel metal if light...
Ch. 2.4 - What is the de Broglie wavelength in meters of a...Ch. 2.6 - Extend Table 2.2 to show allowed combinations of...Ch. 2.6 - Give orbital notations for electrons in orbitals...Ch. 2.6 - Give the allowed combinations of three quantum...Ch. 2.7 - Prob. 2.15PCh. 2.7 - Give a possible combination of n and l quantum...Ch. 2.9 - Calculate in kilojoules per mole the energy...Ch. 2.12 - Look at the electron configurations in Figure...Ch. 2.13 - Give expected ground-state electron configurations...Ch. 2.13 - Take a guess. What do you think is a likely...Ch. 2.13 - Identify the atom with the following ground-state...Ch. 2.14 - Which atom in each of the following pairs would...Ch. 2.14 - Prob. 2.23PCh. 2 - Where on the blank outline of the periodic table...Ch. 2 - Where on the periodic table do elements that meet...Ch. 2 - One of the elements shown on the following...Ch. 2 - Two electromagnetic waves are represented below....Ch. 2 - Prob. 2.28CPCh. 2 - The following orbital-filling diagram represents...Ch. 2 - Prob. 2.30CPCh. 2 - Identify each of the following orbitals, and give...Ch. 2 - Which has the higher frequency, red light or...Ch. 2 - Prob. 2.33SPCh. 2 - The Hubble Space Telescope detects radiant energy...Ch. 2 - Prob. 2.35SPCh. 2 - What is the wavelength in meters of ultraviolet...Ch. 2 - Prob. 2.37SPCh. 2 - Calculate the energies of the following waves in...Ch. 2 - The MRI (magnetic resonance imaging) body scanners...Ch. 2 - A certain cellular telephone transmits at a...Ch. 2 - Prob. 2.41SPCh. 2 - What is the wavelength in meters of photons with...Ch. 2 - What is the energy of each of the following...Ch. 2 - The data encoded on CDs, DVDs, and Blu-ray discs...Ch. 2 - The semimetal germanium is used as a component in...Ch. 2 - Prob. 2.46SPCh. 2 - According to the values cited in Problem 2.46, the...Ch. 2 - The work function of silver metal is 436 kJ/mol....Ch. 2 - What is the work function of gold metal in kJ/mol...Ch. 2 - Protons and electrons can be given very high...Ch. 2 - If a proton (mass = 1.673 1024 g) is accelerated...Ch. 2 - What is the de Broglie wavelength in meters of a...Ch. 2 - What is the de Broglie wavelength in meters of a...Ch. 2 - At what speed in meters per second must a 145 g...Ch. 2 - What velocity would an electron (mass = 9.11 1031...Ch. 2 - Use the Heisenberg uncertainty principle to...Ch. 2 - The mass of a helium-4 atom is 4.0026 u, and its...Ch. 2 - What are the four quantum numbers, and what does...Ch. 2 - What is the Heisenberg uncertainty principle, and...Ch. 2 - Why do we have to use an arbitrary value such as...Ch. 2 - How many nodal surfaces does a 4s orbital have?...Ch. 2 - Prob. 2.62SPCh. 2 - How does electron shielding in multielectron atoms...Ch. 2 - Give the allowable combinations of quantum numbers...Ch. 2 - Give the orbital designations of electrons with...Ch. 2 - Tell which of the following combinations of...Ch. 2 - Which of the following combinations of quantum...Ch. 2 - What is the maximum number of electrons in an atom...Ch. 2 - What is the maximum number of electrons in an atom...Ch. 2 - The wavelength of light at which the Balmer series...Ch. 2 - One series of lines of the hydrogen spectrum is...Ch. 2 - Prob. 2.72SPCh. 2 - Excited rubidium atoms emit red light with = 795...Ch. 2 - Why does the number of elements in successive...Ch. 2 - Prob. 2.75SPCh. 2 - Prob. 2.76SPCh. 2 - Prob. 2.77SPCh. 2 - According to the aufbau principle, which orbital...Ch. 2 - Prob. 2.79SPCh. 2 - Prob. 2.80SPCh. 2 - Give the expected ground-state electron...Ch. 2 - Prob. 2.82SPCh. 2 - Draw orbital-filling diagrams for atoms with the...Ch. 2 - Prob. 2.84SPCh. 2 - Prob. 2.85SPCh. 2 - Prob. 2.86SPCh. 2 - Prob. 2.87SPCh. 2 - Prob. 2.88SPCh. 2 - Prob. 2.89SPCh. 2 - Prob. 2.90SPCh. 2 - Prob. 2.91SPCh. 2 - Prob. 2.92SPCh. 2 - Which atom in each of the following pairs has a...Ch. 2 - Prob. 2.94SPCh. 2 - Prob. 2.95SPCh. 2 - What is the expected ground-state electron...Ch. 2 - Prob. 2.97SPCh. 2 - Orbital energies in single-electron atoms or ions,...Ch. 2 - Prob. 2.99CHPCh. 2 - Prob. 2.100CHPCh. 2 - Prob. 2.101CHPCh. 2 - Prob. 2.102CHPCh. 2 - What is the wavelength in meters of photons with...Ch. 2 - Prob. 2.104CHPCh. 2 - The second in the SI system is defined as the...Ch. 2 - Prob. 2.106CHPCh. 2 - Prob. 2.107CHPCh. 2 - Cesium metal is often used in photoelectric...Ch. 2 - Prob. 2.109CHPCh. 2 - Prob. 2.110CHPCh. 2 - Prob. 2.111CHPCh. 2 - Youre probably familiar with using Scotch Tape for...Ch. 2 - Hard wintergreen-flavored candies are...Ch. 2 - Prob. 2.114CHPCh. 2 - Prob. 2.115CHPCh. 2 - Prob. 2.116CHPCh. 2 - Prob. 2.117CHPCh. 2 - Prob. 2.118CHPCh. 2 - X rays with a wavelength of 1.54 1010 m are...Ch. 2 - Prob. 2.120CHPCh. 2 - Assume that the rules for quantum numbers are...Ch. 2 - Given the subshells 1s, 2s, 2p, 3s, 3p, and 3d,...Ch. 2 - Prob. 2.123CHPCh. 2 - A minimum energy of 7.21 1019 J is required to...Ch. 2 - A photon produced by an X-ray machine has an...Ch. 2 - An energetically excited hydrogen atom has its...Ch. 2 - Prob. 2.127MP
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- describe trace analysis and explain its role in materials testing.arrow_forward6.32 What are the mathematical origins of quantum numbers?arrow_forwardPlanck originated the idea that energies can be quantized. What does the term quantized mean? What was Planck trying to explain when he was led to the concept of quantization of energy? Give the formula he arrived at and explain each of the terms in the formula.arrow_forward
- According to a relationship developed by Niels Bohr, for an atom or ion that has a single electron, the total energy, En, of an electron in a stable orbit of quantum number n is En = [Z2/n2] (2.179 1018 J) where Z is the atomic number. Calculate the ionization energy for the electron in a ground-state He+ ion.arrow_forward6.106 When Bohr devised his model for the atom, was he using deductive or inductive reasoning? Explain your answer.arrow_forwardHow many unpaired electrons are there in an atom of (a) phosphorus? (b) potassium? (c) plutonium (Pu)?arrow_forward
- Why was Schrodinger not able to describe exactly the pathway an electron takes as it moves through the space of an atom?arrow_forwardThe energy of a photon of visible light emitted by an excited atom is the energy change that takes place within the atom itself.arrow_forwardExplain the main features of Bohrs theory. Do these features solve the difficulty alluded to in Question 7.8?arrow_forward
- How does probability fit into the description of the atom?arrow_forwardThe hydrogen atom contains only one electron, but there are several lines in its line emission spectrum (Figure 5.8). How does the Bohr theory explain this?arrow_forward6.105 When we say that the existence of atomic spectra tells us that atoms have specific energy levels, are we using deductive or inductive reasoning?arrow_forward
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