General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Question
Chapter 19.10, Problem 19.7P
Interpretation Introduction
Interpretation:
The electron-dot resonance structure, formal charge and the most important resonance structure has to be given for the molecules in Table 19.6. Also the paramagnetic molecules has to be indicated.
Concept introduction:
Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.
Formal charge=
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Acetylene 1C2H22 and nitrogen 1N22 both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) Byreferring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O51g2 and of acetylene to formCO21g2 and H2O1g2. (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O51g2 is 11.30 kJ>mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.
Acetylene (C2H2) and nitrogen (N2) both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) By referring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O5(g) and of acetylene to formCO2(g) and H2O(g). (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O5(g) is 11.30 kJ/mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.
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Chapter 19 Solutions
General Chemistry: Atoms First
Ch. 19.1 - Prob. 19.1PCh. 19.2 - Prob. 19.2PCh. 19.2 - Prob. 19.3CPCh. 19.4 - Prob. 19.4PCh. 19.7 - Prob. 19.5PCh. 19.8 - Prob. 19.6CPCh. 19.10 - Prob. 19.7PCh. 19.13 - Prob. 19.8CPCh. 19.13 - Prob. 19.9PCh. 19.14 - Prob. 19.10P
Ch. 19 - Prob. 19.11CPCh. 19 - Prob. 19.12CPCh. 19 - Locate the following elements on the periodic...Ch. 19 - Prob. 19.14CPCh. 19 - Prob. 19.15CPCh. 19 - Prob. 19.16CPCh. 19 - Prob. 19.17CPCh. 19 - Prob. 19.18CPCh. 19 - Prob. 19.19CPCh. 19 - Prob. 19.20SPCh. 19 - Prob. 19.21SPCh. 19 - Prob. 19.22SPCh. 19 - Prob. 19.23SPCh. 19 - Prob. 19.24SPCh. 19 - Prob. 19.25SPCh. 19 - Prob. 19.26SPCh. 19 - Prob. 19.27SPCh. 19 - Prob. 19.28SPCh. 19 - Which compound in each of the following pairs is...Ch. 19 - Prob. 19.30SPCh. 19 - Prob. 19.31SPCh. 19 - Prob. 19.32SPCh. 19 - Prob. 19.33SPCh. 19 - Prob. 19.34SPCh. 19 - Prob. 19.35SPCh. 19 - Prob. 19.36SPCh. 19 - Prob. 19.37SPCh. 19 - Prob. 19.38SPCh. 19 - Prob. 19.39SPCh. 19 - Prob. 19.40SPCh. 19 - Prob. 19.41SPCh. 19 - Prob. 19.42SPCh. 19 - Prob. 19.43SPCh. 19 - Prob. 19.44SPCh. 19 - Prob. 19.45SPCh. 19 - Prob. 19.46SPCh. 19 - Prob. 19.47SPCh. 19 - Prob. 19.48SPCh. 19 - Prob. 19.49SPCh. 19 - Prob. 19.50SPCh. 19 - Prob. 19.51SPCh. 19 - Prob. 19.52SPCh. 19 - Prob. 19.53SPCh. 19 - Prob. 19.54SPCh. 19 - Prob. 19.55SPCh. 19 - Prob. 19.56SPCh. 19 - Prob. 19.57SPCh. 19 - Prob. 19.58SPCh. 19 - Prob. 19.59SPCh. 19 - Prob. 19.60SPCh. 19 - Prob. 19.61SPCh. 19 - Prob. 19.62SPCh. 19 - Prob. 19.63SPCh. 19 - Prob. 19.64SPCh. 19 - Prob. 19.65SPCh. 19 - Prob. 19.66SPCh. 19 - Prob. 19.67SPCh. 19 - Prob. 19.68SPCh. 19 - Prob. 19.69SPCh. 19 - Prob. 19.70SPCh. 19 - Draw electron-dot structures for: (a) Nitrous...Ch. 19 - Prob. 19.72SPCh. 19 - Prob. 19.73SPCh. 19 - Prob. 19.74SPCh. 19 - Prob. 19.75SPCh. 19 - Prob. 19.76SPCh. 19 - Prob. 19.77SPCh. 19 - Prob. 19.78SPCh. 19 - Describe the process used for the industrial...Ch. 19 - Prob. 19.80SPCh. 19 - Prob. 19.81SPCh. 19 - Describe the structure of the sulfur molecules in:...Ch. 19 - Prob. 19.83SPCh. 19 - Prob. 19.84SPCh. 19 - Prob. 19.85SPCh. 19 - Describe the contact process for the manufacture...Ch. 19 - Describe a convenient laboratory method for...Ch. 19 - Prob. 19.88SPCh. 19 - Prob. 19.89SPCh. 19 - Prob. 19.90SPCh. 19 - Account for each of the following observations:...Ch. 19 - Prob. 19.92SPCh. 19 - Prob. 19.93SPCh. 19 - Prob. 19.94SPCh. 19 - Prob. 19.95SPCh. 19 - Prob. 19.96SPCh. 19 - Prob. 19.97SPCh. 19 - Prob. 19.98SPCh. 19 - Prob. 19.99SPCh. 19 - Write a balanced net ionic equation for each of...Ch. 19 - Prob. 19.101SPCh. 19 - Prob. 19.102CHPCh. 19 - Prob. 19.103CHPCh. 19 - Prob. 19.104CHPCh. 19 - Prob. 19.105CHPCh. 19 - Prob. 19.106CHPCh. 19 - Prob. 19.107CHPCh. 19 - Prob. 19.108CHPCh. 19 - Prob. 19.109CHPCh. 19 - Prob. 19.110CHPCh. 19 - Prob. 19.111CHPCh. 19 - Prob. 19.112CHPCh. 19 - Prob. 19.113CHPCh. 19 - Which of the group 4A elements have allotropes...Ch. 19 - Prob. 19.115CHPCh. 19 - Prob. 19.116CHPCh. 19 - Prob. 19.117CHPCh. 19 - Prob. 19.118CHPCh. 19 - Prob. 19.119CHPCh. 19 - Prob. 19.120CHPCh. 19 - Prob. 19.121CHPCh. 19 - Prob. 19.122CHPCh. 19 - Prob. 19.123CHPCh. 19 - Prob. 19.124CHPCh. 19 - Prob. 19.125CHPCh. 19 - Prob. 19.126CHPCh. 19 - Give one example from main group chemistry that...Ch. 19 - Prob. 19.128CHPCh. 19 - Prob. 19.129CHPCh. 19 - Prob. 19.130MPCh. 19 - Prob. 19.133MPCh. 19 - Prob. 19.134MP
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