Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Chapter 19, Problem 71QRT
(a)
Interpretation Introduction
Interpretation:
Resonance forms of
(b)
Interpretation Introduction
Interpretation:
Molecular shape and bond angle in
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Compounds such as NaBH4, Al(BH4)3, and LiAlH4 are complex hydrides used as reducing agents in many syntheses.
(a) Give the oxidation state of each element in these compounds.
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Compounds such as NaBH4, Al(BH4)3, and LiAlH4 are complexhydrides used as reducing agents in many syntheses.(a) Give the oxidation state of each element in these compounds.(b) Write a Lewis structure for the polyatomic anion in NaBH4, and predict its shape.
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Chapter 19 Solutions
Chemistry: The Molecular Science
Ch. 19.1 - Prob. 19.1ECh. 19.1 - Prob. 19.2ECh. 19.2 - Prob. 19.3CECh. 19.2 - Prob. 19.4CECh. 19.3 - Prob. 19.5ECh. 19.4 - Prob. 19.1PSPCh. 19.4 - Prob. 19.6ECh. 19.4 - Prob. 19.7ECh. 19.4 - Prob. 19.2PSPCh. 19.5 - Prob. 19.8CE
Ch. 19.5 - Prob. 19.9ECh. 19.5 - Prob. 19.3PSPCh. 19.5 - Use the terms oxidation, reduction, oxidizing...Ch. 19.5 - Prob. 19.11ECh. 19.6 - Prob. 19.13ECh. 19.6 - Prob. 19.14ECh. 19.6 - Prob. 19.15CECh. 19.6 - Prob. 19.16CECh. 19.6 - Prob. 19.4PSPCh. 19.6 - Prob. 19.5PSPCh. 19.6 - Prob. 19.17ECh. 19.6 - Prob. 19.6PSPCh. 19.6 - Prob. 19.7PSPCh. 19.6 - Prob. 19.8PSPCh. 19 - Prob. 1QRTCh. 19 - Prob. 2QRTCh. 19 - Prob. 3QRTCh. 19 - Prob. 4QRTCh. 19 - Prob. 5QRTCh. 19 - Prob. 6QRTCh. 19 - Prob. 7QRTCh. 19 - Prob. 8QRTCh. 19 - Prob. 9QRTCh. 19 - Prob. 10QRTCh. 19 - Prob. 11QRTCh. 19 - Prob. 12QRTCh. 19 - Prob. 13QRTCh. 19 - Prob. 14QRTCh. 19 - Prob. 15QRTCh. 19 - Prob. 16QRTCh. 19 - Prob. 17QRTCh. 19 - Prob. 18QRTCh. 19 - Prob. 19QRTCh. 19 - Prob. 20QRTCh. 19 - Prob. 21QRTCh. 19 - Prob. 22QRTCh. 19 - Prob. 23QRTCh. 19 - Prob. 24QRTCh. 19 - Prob. 25QRTCh. 19 - Prob. 26QRTCh. 19 - Identify the substance or substances produced by...Ch. 19 - Prob. 28QRTCh. 19 - Prob. 29QRTCh. 19 - Prob. 30QRTCh. 19 - Prob. 31QRTCh. 19 - Prob. 32QRTCh. 19 - Prob. 33QRTCh. 19 - Prob. 34QRTCh. 19 - Prob. 35QRTCh. 19 - Prob. 36QRTCh. 19 - Prob. 37QRTCh. 19 - Prob. 38QRTCh. 19 - Prob. 39QRTCh. 19 - Prob. 40QRTCh. 19 - Prob. 41QRTCh. 19 - Prob. 42QRTCh. 19 - A human body contains approximately 5 L of blood....Ch. 19 - Prob. 44QRTCh. 19 - Prob. 45QRTCh. 19 - Prob. 46QRTCh. 19 - Prob. 47QRTCh. 19 - Prob. 48QRTCh. 19 - Prob. 49QRTCh. 19 - Prob. 50QRTCh. 19 - Prob. 51QRTCh. 19 - Prob. 52QRTCh. 19 - Prob. 53QRTCh. 19 - Prob. 54QRTCh. 19 - Prob. 55QRTCh. 19 - Prob. 56QRTCh. 19 - Prob. 57QRTCh. 19 - Prob. 58QRTCh. 19 - Prob. 59QRTCh. 19 - Prob. 60QRTCh. 19 - Prob. 61QRTCh. 19 - Prob. 62QRTCh. 19 - Prob. 63QRTCh. 19 - Prob. 64QRTCh. 19 - Prob. 65QRTCh. 19 - Prob. 66QRTCh. 19 - Prob. 67QRTCh. 19 - Prob. 68QRTCh. 19 - Prob. 69QRTCh. 19 - Prob. 70QRTCh. 19 - Prob. 71QRTCh. 19 - Prob. 72QRTCh. 19 - Prob. 73QRTCh. 19 - Prob. 74QRTCh. 19 - Use the phase diagram for sulfur for Question 75....Ch. 19 - Prob. 76QRTCh. 19 - Prob. 77QRTCh. 19 - Prob. 78QRTCh. 19 - Prob. 79QRTCh. 19 - Prob. 80QRTCh. 19 - A natural brine found in Arkansas has a bromide...Ch. 19 - Prob. 82QRTCh. 19 - Prob. 83QRTCh. 19 - Prob. 84QRTCh. 19 - At 20. C the vapor pressure of white phosphorus is...Ch. 19 - Prob. 86QRTCh. 19 - Assume that the radius of Earth is 6400 km, the...Ch. 19 - Prob. 88QRTCh. 19 - Prob. 89QRTCh. 19 - Prob. 90QRTCh. 19 - Prob. 91QRTCh. 19 - Prob. 92QRTCh. 19 - Prob. 93QRTCh. 19 - Prob. 94QRTCh. 19 - Prob. 95QRTCh. 19 - Use a Born-Haber cycle (Sec. 5-13) to calculate...Ch. 19 - Prob. 97QRTCh. 19 - Elemental analysis of a borane indicates this...Ch. 19 - Prob. 99QRTCh. 19 - Prob. 100QRT
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- (a) Draw the best Lewis structure(s) for the nitrite ion, NO2-.(b) With what allotrope of oxygen is it isoelectronic?(c) What would you predict for the lengths of the bondsin NO2- relative to N¬O single bonds and doublebonds?arrow_forwardChlorine dioxide gas (ClO2) is used as a commercial bleachingagent. It bleaches materials by oxidizing them. In thecourse of these reactions, the ClO2 is itself reduced. (a)What is the Lewis structure for ClO2? (b) Why do you thinkthat ClO2 is reduced so readily? (c) When a ClO2 moleculegains an electron, the chlorite ion, ClO2-, forms. Draw theLewis structure for ClO2-. (d) Predict the O—Cl—O bondangle in the ClO2- ion. (e) One method of preparing ClO2is by the reaction of chlorine and sodium chlorite:Cl2(g) + 2 NaClO2(s)------>2 ClO2(g) + 2 NaCl(s)If you allow 15.0 g of NaClO2 to react with 2.00 L of chlorinegas at a pressure of 1.50 atm at 21 °C, how many gramsof ClO2 can be prepared?arrow_forwardThe elements sodium, aluminum, and chlorine are in the same period. (a) Which has the greatest electronegativity? (b) Which of the atoms is smallest? (c) Which is the largest possible oxidation state for each of these elements? (d) Will the oxide of each element in the highest oxidation state (write its formula) be acidic, basic, or amphoteric?arrow_forward
- (a) What are trihalomethanes (THMs)? (b) Draw the Lewisstructures of two example THMs.arrow_forwardBorane (BH3) is unstable under normal conditions, but it has been detected at lowpressure.(a) Draw the Lewis structure for borane.(b) Draw a diagram of the bonding in BH3, and label the hybridization of each orbital.(c) Predict the H¬B¬H bond anglearrow_forwardAcetylene 1C2H22 and nitrogen 1N22 both contain a triplebond, but they differ greatly in their chemical properties.(a) Write the Lewis structures for the two substances. (b) Byreferring to Appendix C, look up the enthalpies of formationof acetylene and nitrogen. Which compound is more stable?(c) Write balanced chemical equations for the completeoxidation of N2 to form N2O51g2 and of acetylene to formCO21g2 and H2O1g2. (d) Calculate the enthalpy of oxidationper mole for N2 and for C2H2 (the enthalpy of formationof N2O51g2 is 11.30 kJ>mol). (e) Both N2 and C2H2 possesstriple bonds with quite high bond enthalpies (Table 8.3).Calculate the enthalpy of hydrogenation per mole for bothcompounds: acetylene plus H2 to make methane, CH4;nitrogen plus H2 to make ammonia, NH3.arrow_forward
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