Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Question
Chapter 19, Problem 30P
Interpretation Introduction
Interpretation:
The name and structure of the alditol formed by reduction of
Concept Introduction:
The sodium borohydride is a reducing agent, so it reduces the
The reduction of
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Disaccharides are formed from two monosaccharides that are held
glycosidic bond. Glycosidic bonds are found only in carbohydr
Work on your own. Look at the molecules labelled A and B.
Figure 2 Structural formula for glucose showing how (a) a chain becomes (b) a fg
OH-C-H
HO
H-C-OH
H-C-OH
OH
"CH,OH
e diagr
nosac
es up
mbine
Identify monosaccharides
Activity 1
OH HH
ОН ОН
H OH O
C-C-C-C-C-C-H
H-C-C-C
н ОН ОН Н
H.
H H
HO.
molecule A
molecule B
Explain why both molecules A and B are carbohydrates.
Which molecule is a triose and which is a hexose? Explain yu
Write down the chemical formula for each molecule.
Explain why both molecules A and B are monosaccharides
Disaccharides
nk the monosaccharides together.
Table 2 on page 47 ch
homic
From the choices given below select the aldopentose that yields the same alditol as L-ribose upon reduction with NaBH 4.
Select ALL monosaccharides that satisfy the requirement, excluding the structure referenced in the question.
Note that only D structures are shown. To select an L structure click on the name.
If no selection exists, then select the referenced structure.
H
H
H
CHO
OH
OH
OH
CH₂OH
D-Ribose
L-Ribose
HO-
H
H-
CHO
-H
-OH
-OH
CH₂OH
D-Arabinose
L-Arabinose
H
HO
H
CHO
OH
H
-OH
CH₂OH
D-Xylose
L-Xylose
HO
HO-
H-
CHO
H
-H
-OH
CH₂OH
D-Lyxose
L-Lyxose
Name the glycosidic linkage that occurs between molecules C and D in the following
carbohydrate:
CHỊCH
OH
OH
6
CH₂OH
с
OH
B
OH
OH
OH
CHÍNH
OH
OH
0
*use the insert symbol (see below) to show the x or B
D
Chapter 19 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 19.1 - Prob. 19.1QCCh. 19.1 - Prob. 19.2QCCh. 19.2 - Prob. 19.3QCCh. 19.3 - Prob. 19.4QCCh. 19.4 - Prob. 19.5QCCh. 19.5 - Prob. 19.6QCCh. 19 - Prob. 1PCh. 19 - Prob. 2PCh. 19 - Prob. 3PCh. 19 - Prob. 4P
Ch. 19 - Prob. 5PCh. 19 - Prob. 6PCh. 19 - Prob. 7PCh. 19 - Prob. 8PCh. 19 - Prob. 9PCh. 19 - Prob. 10PCh. 19 - Prob. 11PCh. 19 - Prob. 12PCh. 19 - Prob. 13PCh. 19 - Prob. 14PCh. 19 - Prob. 15PCh. 19 - Prob. 16PCh. 19 - Prob. 17PCh. 19 - Prob. 18PCh. 19 - Prob. 19PCh. 19 - Prob. 20PCh. 19 - Prob. 21PCh. 19 - Prob. 22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Prob. 29PCh. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - Prob. 36PCh. 19 - Prob. 37PCh. 19 - Prob. 38PCh. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Prob. 41PCh. 19 - 6 Where is glycogen stored in the human body?Ch. 19 - Prob. 43PCh. 19 - 8 How is it possible that cows can digest grass...Ch. 19 - 1 Hyaluronic acid acts as a lubricant in the...Ch. 19 - Prob. 46PCh. 19 - Prob. 47PCh. 19 - Prob. 48PCh. 19 - Prob. 49PCh. 19 - Prob. 50PCh. 19 - Prob. 51PCh. 19 - Prob. 52PCh. 19 - Prob. 53PCh. 19 - Prob. 54PCh. 19 - Prob. 55PCh. 19 - Prob. 56PCh. 19 - Prob. 57PCh. 19 - Prob. 58PCh. 19 - Prob. 59PCh. 19 - Prob. 60PCh. 19 - Prob. 61PCh. 19 - Prob. 62PCh. 19 - Prob. 63PCh. 19 - Prob. 64PCh. 19 - Prob. 65PCh. 19 - Prob. 66PCh. 19 - Prob. 67PCh. 19 - Prob. 68PCh. 19 - Prob. 69PCh. 19 - Prob. 70PCh. 19 - Prob. 71PCh. 19 - Prob. 72PCh. 19 - Prob. 73PCh. 19 - Prob. 74PCh. 19 - Prob. 75P
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- 14. (a) Identify the acetal and the ketal group in the following disaccharide. (b) Decide whether the compound is a non-reducing or reducing sugar. OH НО HƠ HO Н HO Н НО HO 15. (a) Identify the glycosidic bond in the following disaccharide. (b) Decide whether the compound is a non-reducing or reducing sugar. (c) Polysaccharide units are usually bonded together with a or B 1, 6 or 1, 4 linkages. What linkage is used in the disaccharide shown below? s) НО НО НО HO НО -OH OH -H OH CH2OH 16. Draw the structure for 1,4-B-D-galactopyranosyl-D-glucose. ( но- 17. Assign an R/S designation to each chirality center in the following compound: ( CHO НО -OHarrow_forward. Treatment of fructose with methyliodide produces1,3,4,6-tetra-O-methylfructose. What does this informationtell you about the fructose ring structure?arrow_forwardDescribe the carbohydrate structure depicted below; CH2OH H -CH2 О он он HO OH H OH H OH your answer should specifically indicate (i) the type(s) of isomer, i.e., a- or b-, (ii) the type(s) of ring structures present and (iii) the type of glycosidic linkage presentarrow_forward
- In glycoside formation, the hemiacetal functional group of a cyclic monosaccharide is converted to an acetal group by reaction with a(an)arrow_forwardFor the following fatty acids, indicate the FALSE alternative: a) Stearidonic acid is the most unsaturated. b) Nervonic and erucic acids are ω9. c) Gamma linolenic acid is polyunsaturated and erucic acid is monounsaturated. d) Stearidonic and gamma linolenic acids are ω3. e) All possible triglycerides of these fatty acids will be oils.arrow_forward37- Complete the equation by giving the products of the hydrolysis of lactose. galactose + glucose starch + glycogen fructose + galactose maltose + sucrose fructose + glucose glucose + glucose cellulose + amylosearrow_forward
- The aldonic acid of d-glucose forms a five-membered-ring lactone. Draw its structure.arrow_forwardWhat is 2-deoxyribose ? Explain its importance ?arrow_forwardOH CH₂OH OH OH 1) There are two pyranose rings CH₂OH OH 4) It's a non-reducing sugar. OH MOH 2) The linkage between the 2 monosaccharide units is ß1 → 4. 3) When Cu²+ is added to a solution of the disaccharide shown, a red precipitate will form.arrow_forward
- Question 21 Match the structures with the description NH NH CHO CH HO CH, HO HỌ CH, NICH H. ocit, CH, он он HO но- HO HO он CH2 OH >arrow_forward10 Mark the following statements as true or false, explaining in a few words the reasons for your choice. a) The disaccharide in question 9 is a reducing sugar. b) The reaction of D-fructose with Tollens reagent gives two aldonic acids. c) Morphine and codeine are isomeric compounds. d) Adenine, guanine and cytosine are all purine bases. e) Prostaglandins PGB and PGC have a single O atom in their structure.arrow_forwardThe linkages shown in circles "A" and "B" are what kind of linkages? In other words, what is the general term for the linkages that hold sugar monomers together? CH₂OH R Peptide bonds Ester bonds O Glycosidic Bonds O Amide bonds OH CH₂OH OH OH CH₂ A B КОН (NHCOCHarrow_forward
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