Concept explainers
In each of the following examples, sketch a voltaic cell that uses the reaction. Label the anode and cathode; indicate the direction of electron flow; write a balanced equation for cell reaction; and calculate
a.
b.
c.
d.
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GENERAL CHEMISTRY-MOD.MASTERINGCHEM.
- Another type of battery is the alkaline zinc-mercury cell, in which the cell reaction is Zn(s) + HgO(s) Hg() + ZnO(s) E = + 1.35 V (a) What is the standard free energy change for this reaction? (b) The standard free energy change in a voltaic cell is the maximum electrical energy that the cell can produce. If the reaction in a zinc-mercury cell consumes 1.00 g mercury oxide, what is the standard free energy change? (c) For how many hours could a mercury cell produce a 10-mA current if the limiting reactant is 3.50 g mercury oxide?arrow_forwardFour voltaic cells are set up. In each, one half-cell contains a standard hydrogen electrode. The second half-cell is one of the following: (i) Cr3+(aq, 1.0 M)|Cr(s) (ii) Fea+(aq, 1.0M)|Fe(s) (iii) Cu2+(aq, 1.0M)|Cu(s) (iv) Mg2+(aq, 1.0M)|Mg(s) (a) In which of the voltaic cells does the hydrogen electrode serve as the cathode? (b) Which voltaic cell produces the highest potential? Which produces the lowest potential?arrow_forwardCalculate the standard cell potential of the cell corresponding to the oxidation of oxalic acid, H2C2O4, by permanganate ion. MnO4. 5H2C2O4(aq)+2MnO4(aq)+6H+(aq)10CO2(g)+2Mn2+(aq)+8H2O(l) See Appendix C for free energies of formation: Gf for H2C2O4(aq) is 698 kJ.arrow_forward
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- Consider a galvanic cell based on the following half-reactions: a. What is the expected cell potential with all components in their standard states? b. What is the oxidizing agent in the overall cell reaction? c. What substances make up the anode compartment? d. In the standard cell, in which direction do the electrons flow? e. How many electrons are transferred per unit of cell reaction? f. If this cell is set up at 25C with [Fe2+] = 2.00 104 M and [La3+] = 3.00 103 M, what is the expected cell potential?arrow_forwardConsider the following galvanic cell: Calculate the concentrations of Ag+(aq) and Ni2+(aq) once the cell is dead.arrow_forward
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